The synthesis of molecules that feature main-group elements in unusual oxidation states
and coordination environments is a primary pursuit of main-group chemistry. The p-block …

Given the alleged extreme toxicity of beryllium and its compounds, it is the least investigated
nonradioactive element. However, beryllium exhibits unique properties among the elements …

Substitution of a C= C bond by an isoelectronic B–N bond is a well-established strategy to
alter the electronic structure and stability of acenes. BN-substituted acenes that possess …

The alkaline-earth elements (Be, Mg, Ca, Sr, and Ba) strongly favor the formation of
diamagnetic compounds in the+ 2 oxidation state. Herein we report a paramagnetic …

We report a comprehensive assessment of Lewis acidity for a series of carbone-stibenium
and-bismuthenium ions using the Gutmann–Beckett (GB) method. These new antimony and …

Borenium ions, originally synthesized as fundamentally important laboratory curiosities,
have attracted significant attention due to their applications in catalysis and frustrated Lewis …

This paper discusses the legislative response to handling beryllium and its compounds as
well as the administrative regulations resulting from their classification as potential human …

A Neutral Beryllium(I) Radical - Czernetzki - 2021 - Angewandte Chemie International Edition -
Wiley Online Library Skip to Article Content Skip to Article Information Wiley Online Library …

We report a combined experimental and theoretical study on the first examples of
carbodicarbene (CDC)‐stabilized bismuth complexes, which feature low‐coordinate cationic …

The first examples of N‐heterocyclic carbene (NHC) and cyclic (alkyl)(amino) carbene
(CAAC) stabilized borepinium and borafluorenium heterocycles are reported herein. The …