Highly efficient ethylene production via electrocatalytic hydrogenation of acetylene under mild conditions

S Wang, K Uwakwe, L Yu, J Ye, Y Zhu, J Hu… - Nature …, 2021 - nature.com
Renewable energy-based electrocatalytic hydrogenation of acetylene to ethylene (E-HAE)
under mild conditions is an attractive substitution to the conventional energy-intensive …

Advances and mechanistic insights in the catalytic semi-hydrogenation of acetylene over non-metallic catalysts

F Zhang, Q Zhang, Y Chen, L Xu, Z Li, Q Wang… - Applied Catalysis A …, 2023 - Elsevier
Acetylene semi-hydrogenation reaction is a critical transformation process for removing
trace levels of acetylene from industrial ethylene streams. Noble metal catalysts are …

Graphene-based carbocatalysts for carbon–carbon bond formation

MS Ahmad, Y Nishina - Nanoscale, 2020 - pubs.rsc.org
Organic transformations are usually catalyzed by metal-based catalysts. In contrast, metal-
free catalysts have attracted considerable attention from the viewpoint of sustainability and …

Efficient industrial-current-density acetylene to polymer-grade ethylene via hydrogen-localization transfer over fluorine-modified copper

L Bai, Y Wang, Z Han, J Bai, K Leng, L Zheng… - Nature …, 2023 - nature.com
Electrocatalytic acetylene semi-hydrogenation to ethylene powered by renewable electricity
represents a sustainable pathway, but the inadequate current density and single-pass yield …

Selective hydrogenation of acetylene to ethylene on anatase TiO 2 through first-principles studies

Q Wan, Y Chen, S Zhou, J Lin, S Lin - Journal of Materials Chemistry A, 2021 - pubs.rsc.org
Titanium dioxide (TiO2) alone is rarely reported to have exciting performance towards
heterogeneous hydrogenation reactions. In this work, we demonstrate via density functional …

Disrupted Spin Degeneracy Promoted C≡ C Triple Bond Activation for Efficient Electrochemical Acetylene Semihydrogenation

M Yuan, H Jiang, R Jiang, Z Wang, ZH Zhao, B Su… - ACS …, 2024 - ACS Publications
Disrupting the spin degeneracy of the electrocatalyst and further manipulating the related
orbital electron arrangement are highly desirable for activating acetylene molecules. Herein …

Tuning electronic structure of palladium from wheat flour-derived N-doped mesoporous carbon for efficient selective hydrogenation of acetylene

Q Wang, J Zhao, L Xu, L Yu, Z Yao, G Lan, L Guo… - Applied Surface …, 2021 - Elsevier
Designing efficient and sustainable catalysts for semi-hydrogenation of acetylene is of
critical importance, but challenging. A novel and easily scaled-up strategy is described in …

Active Sites and Their Individual Turnover Frequencies for Ethylene Hydrogenation on Reduced Graphene Aerogel

K Yalcin, SF Kurtoğlu-Öztulum, FE Sarac Oztuna… - Langmuir, 2024 - ACS Publications
Graphene aerogel (GA) was reduced at various temperatures to prepare a series of reduced
graphene aerogels (rGAs) with different surface characteristics. Detailed characterization …

[HTML][HTML] Enhancement of electrical conductivity of hydrazine-reduced graphene oxide under thermal annealing in hydrogen atmosphere

RM Rudenko, OO Voitsihovska, VN Poroshin - Materials Letters, 2023 - Elsevier
The effect of further thermal annealing in a hydrogen atmosphere on the electrical properties
of hydrazine-reduced graphene oxide (RGO) was investigated. It was found that heat …

Janus-structured graphene scaffold for bottom-up lithium deposition: A progressive gradient approach

Z Du, X Chen, Y Zhao, Y Liu, W Ai - Applied Materials Today, 2024 - Elsevier
Graphene-based materials have been explored as hosts for Li metal anodes, but their high
interfacial activity and short diffusion distances frequently result in dendrite formation on the …