Metallomimetic chemistry of boron
The study of main-group molecules that behave and react similarly to transition-metal (TM)
complexes has attracted significant interest in recent decades. Most notably, the attractive …
complexes has attracted significant interest in recent decades. Most notably, the attractive …
Small molecule activation with bimetallic systems: a landscape of cooperative reactivity
M Navarro, JJ Moreno, M Pérez-Jiménez… - Chemical …, 2022 - pubs.rsc.org
There is growing interest in the design of bimetallic cooperative complexes, which have
emerged due to their potential for bond activation and catalysis, a feature widely exploited …
emerged due to their potential for bond activation and catalysis, a feature widely exploited …
Automated iterative Csp3–C bond formation
Fully automated synthetic chemistry would substantially change the field by providing broad
on-demand access to small molecules. However, the reactions that can be run …
on-demand access to small molecules. However, the reactions that can be run …
Single‐electron transfer in frustrated Lewis pair chemistry
Abstract Frustrated Lewis pairs (FLPs) are well known for their ability to activate small
molecules. Recent reports of radical formation within such systems indicate single‐electron …
molecules. Recent reports of radical formation within such systems indicate single‐electron …
Dihydrogen Activation with a Neutral, Intermolecular Silicon (IV)‐Amine Frustrated Lewis Pair
The heterolytic cleavage of dihydrogen constitutes the hallmark reaction of frustrated Lewis
pairs (FLP). While being well‐established for planar Lewis acids, such as boranes or …
pairs (FLP). While being well‐established for planar Lewis acids, such as boranes or …
From structure to novel reactivity in frustrated Lewis pairs
J Paradies - Coordination Chemistry Reviews, 2019 - Elsevier
The coexistence of a strong Lewis acid and a Lewis base in solution, the so called frustrated
Lewis pair, has led to the discovery of metal-free hydrogen activation. Since then, this …
Lewis pair, has led to the discovery of metal-free hydrogen activation. Since then, this …
Experimental and computational aspects of molecular frustrated Lewis pairs for CO 2 hydrogenation: en route for heterogeneous systems?
RK Riddhi, F Penas-Hidalgo, H Chen… - Chemical Society …, 2024 - pubs.rsc.org
Catalysis plays a crucial role in advancing sustainability. The unique reactivity of frustrated
Lewis pairs (FLPs) is driving an ever-growing interest in the transition metal-free …
Lewis pairs (FLPs) is driving an ever-growing interest in the transition metal-free …
Photoinduced and Thermal Single‐Electron Transfer to Generate Radicals from Frustrated Lewis Pairs
Archetypal phosphine/borane frustrated Lewis pairs (FLPs) are famed for their ability to
activate small molecules. The mechanism is generally believed to involve two‐electron …
activate small molecules. The mechanism is generally believed to involve two‐electron …
Activation of Small Molecules and Hydrogenation of CO2 Catalyzed by Frustrated Lewis Pairs
The chemistry of frustrated Lewis pair (FLP) is widely explored in the activation of small
molecules, the hydrogenation of CO2, and unsaturated organic species. A survey of several …
molecules, the hydrogenation of CO2, and unsaturated organic species. A survey of several …
Evidence for the encounter complex in frustrated Lewis pair chemistry
AR Jupp - Dalton Transactions, 2022 - pubs.rsc.org
Frustrated Lewis Pairs (FLPs) are combinations of bulky Lewis acids and bases that can
carry out small-molecule activation and catalysis. Mechanistically, the reaction of the acid …
carry out small-molecule activation and catalysis. Mechanistically, the reaction of the acid …