[HTML][HTML] Electronic structure and magnetic anisotropy design of functional metal complexes

A Raza, M Perfetti - Coordination Chemistry Reviews, 2023 - Elsevier
Chemical guidelines to target a well-defined electronic structure and magnetic anisotropy
are of primary importance in physics, chemistry and biology. Our literature overview …

Endohedral metallofullerene molecular nanomagnets

Z Hu, S Yang - Chemical Society Reviews, 2024 - pubs.rsc.org
Magnetic lanthanide (Ln) metal complexes exhibiting magnetic bistability can behave as
molecular nanomagnets, also known as single-molecule magnets (SMMs), suitable for …

A Complete Ab Initio View of Orbach and Raman Spin–Lattice Relaxation in a Dysprosium Coordination Compound

M Briganti, F Santanni, L Tesi, F Totti… - Journal of the …, 2021 - ACS Publications
The unique electronic and magnetic properties of lanthanide molecular complexes place
them at the forefront of the race toward high-temperature single-molecule magnets and …

Enhancement of Electromagnetic Wave Attenuation through Polarization Loss Induced by Hybridization of Rare‐Earth 4f and Mo‐4d Orbitals in Liquid Plasma

J Wen, S Hui, Q Chang, G Chen… - Advanced Functional …, 2024 - Wiley Online Library
The incorporation of large‐sized rare earth (RE) elements with high coordination
characteristics into transition metal dichalcogenide (TMD) absorbers while preserving a high …

Emerging trends on designing high-performance dysprosium (III) single-molecule magnets

TG Ashebr, H Li, X Ying, XL Li, C Zhao, S Liu… - ACS Materials …, 2022 - ACS Publications
The present prospect of single-molecule magnets (SMMs) research is more appealing after
the detection of magnetic remanence above liquid-nitrogen temperatures. From the current …

Magnetic 3d–4f chiral clusters showing multimetal site magneto-chiral dichroism

X Wang, SQ Wang, JN Chen, JH Jia… - Journal of the …, 2022 - ACS Publications
Here, we report the molecular self-assembly of hydroxido-bridged {Ln5Ni6}((Ln3+= Dy3+,
Y3+) metal clusters by the reaction of enantiopure chiral ligands, namely,(R/S)-(2-hydroxy-3 …

Optical Readout of Single-Molecule Magnets Magnetic Memories with Unpolarized Light

MS Raju, K Paillot, I Breslavetz, G Novitchi… - Journal of the …, 2024 - ACS Publications
Magnetic materials are widely used for many technologies in energy, health, transportation,
computation, and data storage. For the latter, the readout of the magnetic state of a medium …

Discovery of a dysprosium metallocene single-molecule magnet with two high-temperature Orbach processes

FS Guo, M He, GZ Huang, SR Giblin… - Inorganic …, 2022 - ACS Publications
Magnetic bistability in single-molecule magnets (SMMs) is a potential basis for new types of
nanoscale information storage material. The standard model for thermally activated …

Designing quantum spaces of higher dimensionality from a tetranuclear erbium-based single-molecule magnet

AP Orlova, MG Bernbeck… - Journal of the American …, 2024 - ACS Publications
The spin relaxation of an Er3+ tetranuclear single-molecule magnet,[Er (hdcCOT) I]
4,(hdcCOT= hexahydrodicyclopentacyclooctatetraenide dianion), is modeled as a near …

Slow Magnetic Relaxation in a Californium Complex

LM Aguirre Quintana, DJ Lussier… - Journal of the …, 2024 - ACS Publications
We report the synthesis and characterization of the macrocyclic californium derivative Na [Cf
(H2O)(DOTA)](DOTA= 1, 4, 7, 10-tetraazacyclododecane-1, 4, 7, 10-tetraacetate), 1-Cf …