Chiroptical properties of symmetric double, triple, and multiple helicenes

T Mori - Chemical Reviews, 2021 - ACS Publications
Helicenes have attracted considerable attention due to their inherent helical chirality and
extended π-conjugation. Recently, rapid progress has been witnessed in the preparation of …

Supramolecular chiroptical switches

L Zhang, HX Wang, S Li, M Liu - Chemical Society Reviews, 2020 - pubs.rsc.org
Chiroptical switches, whose chiral optical signals such as optical rotatory dispersion (ORD),
circular dichroism (CD) and circularly polarized luminescence (CPL) are reversibly …

Enantioenriched helicenes and helicenoids containing main-group elements (B, Si, N, P)

K Dhbaibi, L Favereau, J Crassous - Chemical reviews, 2019 - ACS Publications
In this review, we discuss the rich chemistry of helicenes and helicenoids containing main-
group elements. Enantioenriched helicenic derivatives containing main-group elements B …

Circularly polarized luminescence and circular dichroisms in small organic molecules: correlation between excitation and emission dissymmetry factors

H Tanaka, Y Inoue, T Mori - ChemPhotoChem, 2018 - Wiley Online Library
Prompted by the recent rapid growth of interest in circularly polarized luminescence (CPL) of
organic molecules, we have collected all the reliable CPL, as well as the corresponding …

The added value of small-molecule chirality in technological applications

JR Brandt, F Salerno, MJ Fuchter - Nature Reviews Chemistry, 2017 - nature.com
Chirality is a fundamental symmetry property; chiral objects, such as chiral small molecules,
exist as a pair of non-superimposable mirror images. Although small-molecule chirality is …

Main-group-based electro-and photoactive chiral materials

F Pop, N Zigon, N Avarvari - Chemical reviews, 2019 - ACS Publications
This Review discusses the structure–property relationships in chiral molecules,
macromolecules (polymers), and supramolecules (crystals, liquid crystals, or thin films) …

Chirality amplified: long, discrete helicene nanoribbons

X **ao, SK Pedersen, D Aranda, J Yang… - Journal of the …, 2020 - ACS Publications
Here we report the synthesis of two polyhelicene frameworks consisting, from end-to-end, of
18 and 24 fused benzene rings. The latter exhibits the largest electronic circular dichroism in …

Symmetry-based rational design for boosting chiroptical responses

H Tanaka, M Ikenosako, Y Kato, M Fujiki… - Communications …, 2018 - nature.com
Chiral molecules play indispensable roles in advanced materials and technologies.
Nevertheless, no conventional, yet reliable logical strategies are available for designing …

Octagon‐embedded carbohelicene as a chiral motif for circularly polarized luminescence emission of saddle‐helix nanographenes

MA Medel, R Tapia, V Blanco, D Miguel… - Angewandte …, 2021 - Wiley Online Library
We report a new family of hexa‐peri‐hexabenzocoronene (HBC)‐based helical
nanographenes incorporating π‐extended carbo [5] helicenes bearing an octagonal …

Coordination versatility of NHC-metal topologies in asymmetric catalysis: Synthetic insights and recent trends

A Jayaraj, AV Raveedran, AT Latha… - Coordination Chemistry …, 2023 - Elsevier
Asymmetric metal based catalysis has advanced quickly in recent years, with its efficiency
relying exclusively on chiral ligands. Rational design and meticulous selection of chiral …