Photoactive copper complexes: properties and applications

J Beaudelot, S Oger, S Perusko, TA Phan… - Chemical …, 2022 - ACS Publications
Photocatalyzed and photosensitized chemical processes have seen growing interest
recently and have become among the most active areas of chemical research, notably due …

Two-coordinate thermally activated delayed fluorescence coinage metal complexes: Molecular design, photophysical characters, and device application

TY Li, SJ Zheng, PI Djurovich, ME Thompson - Chemical Reviews, 2024 - ACS Publications
Since the emergence of the first green light emission from a fluorescent thin-film organic light
emitting diode (OLED) in the mid-1980s, a global consumer market for OLED displays has …

Mechano-stimulus and environment-dependent circularly polarized TADF in chiral copper (I) complexes and their application in OLEDs

AMT Muthig, O Mrozek, T Ferschke… - Journal of the …, 2023 - ACS Publications
Molecular emitters that combine circularly polarized luminescence (CPL) and high radiative
rate constants of the triplet exciton decay are highly attractive for electroluminescent devices …

A Configurationally Confined Thermally Activated Delayed Fluorescent Two‐Coordinate CuI Complex for Efficient Blue Electroluminescence

HJ Wang, Y Liu, B Yu, SQ Song… - Angewandte Chemie …, 2023 - Wiley Online Library
Thermally activated delayed fluorescence (TADF) from linear two‐coordinate coinage metal
complexes is sensitive to the geometric arrangement of the ligands. Herein we realize the …

A Rising Star: Luminescent Carbene‐Metal‐Amide Complexes

A Ying, S Gong - Chemistry–A European Journal, 2023 - Wiley Online Library
Coinage metal (gold, silver, and copper) complexes are attractive candidates to substitute
the widely studied noble metal complexes, such as, iridium (III) and platinum (II), as …

Two-coordinate coinage metal complexes as solar photosensitizers

CN Muniz, CA Archer, JS Applebaum… - Journal of the …, 2023 - ACS Publications
Generating sustainable fuel from sunlight plays an important role in meeting the energy
demands of the modern age. Herein, we report two-coordinate carbene-metal-amide (cMa …

Intersystem crossing, phosphorescence, and spin-orbit coupling. Two contrasting Cu (I)-TADF dimers investigated by milli-to micro-second phosphorescence, femto …

H Yersin, R Czerwieniec, U Monkowius… - Coordination Chemistry …, 2023 - Elsevier
Applying femto-second time-resolved spectroscopy, we study intersystem crossing times τ
(ISC) of two Cu (I) dimers, Cu 2 Cl 2 (dppb) 2 1 (dppb= 1, 2-bis-diphenylphosphino) …

Simultaneous Thermally Stimulated Delayed Phosphorescence (TSDP) and Thermally Activated Delayed Fluorescence (TADF) in a Two-Coordinated Au (I) Bimetallic …

SJ Zheng, J Ma, J Su, PI Djurovich… - Journal of the …, 2024 - ACS Publications
A bimetallic, two-coordinated carbene-metal-amine (cMa) Au (I) complex featuring a twisted
tandem carbene structure (NHC1-Au-NHC2-Au-carbazolyl) was synthesized. The molecular …

Au (I)‐TADF Emitters for High Efficiency Full‐Color Vacuum‐Deposited OLEDs and TADF‐Sensitized Fluorescent OLEDs with Ultrahigh Brightness and Prolonged …

R Tang, S Xu, L Du, FF Hung, TL Lam… - Advanced Optical …, 2023 - Wiley Online Library
Herein a class of structurally simple and operationally stable Au (I)‐TADF (TADF= thermally
activated delayed fluorescence) materials, based on a carbene–metal–amide (CMA) …

Ag (i) emitters with ultrafast spin-flip dynamics for high-efficiency electroluminescence

A Ying, N Li, X Chen, J **a, C Yang, S Gong - Chemical Science, 2025 - pubs.rsc.org
Carbene-metal-amide (CMA) complexes are appealing emitters for organic light-emitting
diodes (OLEDs). However, little is known about silver (I)-CMA complexes, particularly …