Ni-catalyzed C–S bond construction and cleavage

S Huang, M Wang, X Jiang - Chemical Society Reviews, 2022 - pubs.rsc.org
Sulfur-containing compounds have attracted considerable interest due to their wide-ranging
applications in pharmaceuticals, agriculture, natural products, and organic materials. The …

Manganese-catalyzed hydrogenation, dehydrogenation, and hydroelementation reactions

K Das, S Waiba, A Jana, B Maji - Chemical Society Reviews, 2022 - pubs.rsc.org
The emerging field of organometallic catalysis has shifted towards research on Earth-
abundant transition metals due to their ready availability, economic advantage, and novel …

Borrowing hydrogen for organic synthesis

BG Reed-Berendt, DE Latham, MB Dambatta… - ACS central …, 2021 - ACS Publications
Borrowing hydrogen is a process that is used to diversify the synthetic utility of commodity
alcohols. A catalyst first oxidizes an alcohol by removing hydrogen to form a reactive …

Harnessing alcohols as sustainable reagents for late-stage functionalisation: synthesis of drugs and bio-inspired compounds

S Bera, LM Kabadwal, D Banerjee - Chemical Society Reviews, 2024 - pubs.rsc.org
Alcohol is ubiquitous with unparalleled structural diversity and thus has wide applications as
a native functional group in organic synthesis. It is highly prevalent among biomolecules and …

Transition-metal mediated carbon–sulfur bond activation and transformations: an update

J Lou, Q Wang, P Wu, H Wang, YG Zhou… - Chemical Society …, 2020 - pubs.rsc.org
Carbon–sulfur bond cross-coupling has become more and more attractive as an alternative
protocol to establish carbon–carbon and carbon–heteroatom bonds. Diverse …

Beyond classical sulfone chemistry: metal-and photocatalytic approaches for C–S bond functionalization of sulfones

J Corpas, SH Kim-Lee, P Mauleón… - Chemical Society …, 2022 - pubs.rsc.org
The exceptional versatility of sulfones has been extensively exploited in organic synthesis
across several decades. Since the first demonstration in 2005 that sulfones can participate …

Manganese-catalyzed cyclopropanation of allylic alcohols with sulfones

K Yu, Q Nie, Q Chen, W Liu - Nature Communications, 2024 - nature.com
Cyclopropanes are among the most important structural units in natural products,
pharmaceuticals, and agrochemicals. Herein, we report a manganese-catalyzed …

Cobalt (III) Complexes of Pyridine-Functionalized Chelating NHC Ligands: Effective Catalysts for the Olefination of Alcohols Using Sulfones

M Siddique, M Das, A Rit - Organometallics, 2024 - ACS Publications
Several air-stable cobalt (III) complexes 1a-d featuring pyridine-functionalized NHC ligand
systems were synthesized and completely characterized. These complexes were then …

Manganese (I)-pincer catalyzed α-alkylation of sulfones by alcohols

L Lu, J Luo, D Milstein - ACS Catalysis, 2023 - ACS Publications
Sulfones are building blocks in organic synthesis and pharmaceutical chemistry. Direct α-
alkylation of sulfones using alcohols with water as the sole byproduct is an efficient and …

Electrochemically Induced Synthesis of Sulfonylated N-Unsubstituted Enamines from Vinyl Azides and Sulfonyl Hydrazides

OM Mulina, NV Zhironkina, SA Paveliev… - Organic …, 2020 - ACS Publications
Sulfonylated N-unsubstituted enamines were synthesized through a chain of chemical and
electrochemical transformations via sulfonylation of vinyl azides. The disclosing of the N …