From stable radicals to thermally robust high-spin diradicals and triradicals
Stable radicals and thermally robust high-spin di-and triradicals have emerged as important
organic materials due to their promising applications in diverse fields. New fundamental …
organic materials due to their promising applications in diverse fields. New fundamental …
Electrical and spin switches in single‐molecule junctions
Single‐molecule electrical and spin switches have been one of the main research focuses in
molecular electronics and spintronics because they may form the most important elements …
molecular electronics and spintronics because they may form the most important elements …
High-Spin S = 3/2 Ground-State Aminyl Triradicals: Toward High-Spin Oligo-Aza Nanographenes
H Zhang, M Pink, Y Wang, S Rajca… - Journal of the American …, 2022 - ACS Publications
We report high-spin aminyl triradicals with near-planar triphenylene backbones. Near-
planarity of the fused aminyl radicals and the 2, 6, 10-triphenylene ferromagnetic coupling …
planarity of the fused aminyl radicals and the 2, 6, 10-triphenylene ferromagnetic coupling …
Spin-State Manipulation in a Luminescent Diradical Polymer
S Wang, X Wang, J Ding, Z Zhu, J Wang, L Shen… - …, 2024 - ACS Publications
Controlling the spin states to modulate their optical properties is crucial for spintronics and
emerging quantum technologies. Open-shell luminescent diradicals are promising …
emerging quantum technologies. Open-shell luminescent diradicals are promising …
Organic neutral radical emitters: Impact of chemical substitution and electronic-state hybridization on the luminescence properties
Neutral donor–acceptor (D–A•) organic radicals have recently attracted a great deal of
attention as promising luminescent materials due to their strong doublet emission. Here, we …
attention as promising luminescent materials due to their strong doublet emission. Here, we …
An Air-Stable Carbon-Centered Triradical with a Well-Addressable Quartet Ground State
D Zhang, Z Zhu, X **ao, YH Fang, T **ao… - Journal of the …, 2024 - ACS Publications
Organic polyradicals with a high-spin ground state and quantum magnetic properties
suitable for spin manipulation are valuable materials for diverse innovative technologies …
suitable for spin manipulation are valuable materials for diverse innovative technologies …
Thermally and magnetically robust triplet ground state diradical
N Gallagher, H Zhang, T Junghoefer… - Journal of the …, 2019 - ACS Publications
High spin (S= 1) organic diradicals may offer enhanced properties with respect to several
emerging technologies, but typically exhibit low singlet triplet energy gaps and possess …
emerging technologies, but typically exhibit low singlet triplet energy gaps and possess …
The fabrication, characterization and functionalization in molecular electronics
Developments in advanced manufacturing have promoted the miniaturization of
semiconductor electronic devices to a near-atomic scale, which continuously follows the'top …
semiconductor electronic devices to a near-atomic scale, which continuously follows the'top …
Synthesis and Thin Films of Thermally Robust Quartet (S = 3/2) Ground State Triradical
C Shu, M Pink, T Junghoefer, E Nadler… - Journal of the …, 2021 - ACS Publications
High-spin (S= 3/2) organic triradicals may offer enhanced properties with respect to several
emerging technologies, but those synthesized to date typically exhibit small doublet quartet …
emerging technologies, but those synthesized to date typically exhibit small doublet quartet …
Perspectives for polychlorinated trityl radicals
An organic free radical is a molecule with one or more unpaired electrons. Although most
free radicals are highly reactive, chemists have developed a few families of so-called …
free radicals are highly reactive, chemists have developed a few families of so-called …