From stable radicals to thermally robust high-spin diradicals and triradicals

C Shu, Z Yang, A Rajca - Chemical Reviews, 2023 - ACS Publications
Stable radicals and thermally robust high-spin di-and triradicals have emerged as important
organic materials due to their promising applications in diverse fields. New fundamental …

Electrical and spin switches in single‐molecule junctions

G Ke, C Duan, F Huang, X Guo - InfoMat, 2020 - Wiley Online Library
Single‐molecule electrical and spin switches have been one of the main research focuses in
molecular electronics and spintronics because they may form the most important elements …

High-Spin S = 3/2 Ground-State Aminyl Triradicals: Toward High-Spin Oligo-Aza Nanographenes

H Zhang, M Pink, Y Wang, S Rajca… - Journal of the American …, 2022 - ACS Publications
We report high-spin aminyl triradicals with near-planar triphenylene backbones. Near-
planarity of the fused aminyl radicals and the 2, 6, 10-triphenylene ferromagnetic coupling …

Spin-State Manipulation in a Luminescent Diradical Polymer

S Wang, X Wang, J Ding, Z Zhu, J Wang, L Shen… - …, 2024 - ACS Publications
Controlling the spin states to modulate their optical properties is crucial for spintronics and
emerging quantum technologies. Open-shell luminescent diradicals are promising …

Organic neutral radical emitters: Impact of chemical substitution and electronic-state hybridization on the luminescence properties

E Cho, V Coropceanu, JL Brédas - Journal of the American …, 2020 - ACS Publications
Neutral donor–acceptor (D–A•) organic radicals have recently attracted a great deal of
attention as promising luminescent materials due to their strong doublet emission. Here, we …

An Air-Stable Carbon-Centered Triradical with a Well-Addressable Quartet Ground State

D Zhang, Z Zhu, X **ao, YH Fang, T **ao… - Journal of the …, 2024 - ACS Publications
Organic polyradicals with a high-spin ground state and quantum magnetic properties
suitable for spin manipulation are valuable materials for diverse innovative technologies …

Thermally and magnetically robust triplet ground state diradical

N Gallagher, H Zhang, T Junghoefer… - Journal of the …, 2019 - ACS Publications
High spin (S= 1) organic diradicals may offer enhanced properties with respect to several
emerging technologies, but typically exhibit low singlet triplet energy gaps and possess …

The fabrication, characterization and functionalization in molecular electronics

Y Zhao, W Liu, J Zhao, Y Wang, J Zheng… - … Journal of Extreme …, 2022 - iopscience.iop.org
Developments in advanced manufacturing have promoted the miniaturization of
semiconductor electronic devices to a near-atomic scale, which continuously follows the'top …

Synthesis and Thin Films of Thermally Robust Quartet (S = 3/2) Ground State Triradical

C Shu, M Pink, T Junghoefer, E Nadler… - Journal of the …, 2021 - ACS Publications
High-spin (S= 3/2) organic triradicals may offer enhanced properties with respect to several
emerging technologies, but those synthesized to date typically exhibit small doublet quartet …

Perspectives for polychlorinated trityl radicals

I Ratera, J Vidal-Gancedo, D Maspoch… - Journal of Materials …, 2021 - pubs.rsc.org
An organic free radical is a molecule with one or more unpaired electrons. Although most
free radicals are highly reactive, chemists have developed a few families of so-called …