[HTML][HTML] A comprehensive overview of directing groups applied in metal-catalysed C–H functionalisation chemistry

C Sambiagio, D Schönbauer, R Blieck… - Chemical Society …, 2018 - pubs.rsc.org
The present review is devoted to summarizing the recent advances (2015–2017) in the field
of metal-catalysed group-directed C–H functionalisation. In order to clearly showcase the …

Transition-metal-catalyzed cross-couplings through carbene migratory insertion

Y ** new methods for the efficient construction of
organic molecules via disconnections other than traditional functional group transformations …

Transition-metal-catalyzed cleavage of C–N single bonds

K Ouyang, W Hao, WX Zhang, Z ** - Chemical Reviews, 2015 - ACS Publications
The C− N bond is one of the most abundant chemical bonds and widely exists in many
organic molecules and biomacromolecules. The formation and transformation of C− N …

Mechanistic view of Ru-catalyzed C–H bond activation and functionalization: computational advances

C Shan, L Zhu, LB Qu, R Bai, Y Lan - Chemical Society Reviews, 2018 - pubs.rsc.org
Ru-Catalyzed aromatic C–H bond activation and functionalization have emerged as
important topics because they have resulted in remarkable progress in organic synthesis …

Cross‐Coupling of α‐Carbonyl Sulfoxonium Ylides with C− H Bonds

M Barday, C Janot, NR Halcovitch, J Muir… - Angewandte …, 2017 - Wiley Online Library
The functionalization of carbon–hydrogen bonds in non‐nucleophilic substrates using α‐
carbonyl sulfoxonium ylides has not been so far investigated, despite the potential safety …

Mechanism of rhodium-catalyzed C–H functionalization: advances in theoretical investigation

X Qi, Y Li, R Bai, Y Lan - Accounts of Chemical Research, 2017 - ACS Publications
Conspectus Transition-metal-catalyzed cross-coupling has emerged as an effective strategy
for chemical synthesis. Within this area, direct C–H bond transformation is one of the most …

Cycloaddition reactions of enoldiazo compounds

QQ Cheng, Y Deng, M Lankelma… - Chemical Society Reviews, 2017 - pubs.rsc.org
Enoldiazo esters and amides have proven to be versatile reagents for cycloaddition
reactions that allow highly efficient construction of various carbocycles and heterocycles …

Experimental and theoretical studies on rhodium-catalyzed coupling of benzamides with 2, 2-difluorovinyl tosylate: diverse synthesis of fluorinated heterocycles

JQ Wu, SS Zhang, H Gao, Z Qi, CJ Zhou… - Journal of the …, 2017 - ACS Publications
Fluorinated heterocycles play an important role in pharmaceutical and agrochemical
industries. Herein, we report on the synthesis of four types of fluorinated heterocycles via …