Ensemble effect for single-atom, small cluster and nanoparticle catalysts

Y Guo, M Wang, Q Zhu, D **ao, D Ma - Nature Catalysis, 2022 - nature.com
A large family of heterogeneous catalytic reactions require active sites with more than one
metal atom, that is, an ensemble of metal atoms. The ensemble requirement, which refers to …

Atomically precise control in the design of low-nuclearity supported metal catalysts

S Mitchell, J Pérez-Ramírez - Nature Reviews Materials, 2021 - nature.com
Nanostructured catalysts incorporating supported metal atoms or small clusters of defined
size and chemical composition attract considerable attention because of their potential to …

Liquid Fluxional Ga Single Atom Catalysts for Efficient Electrochemical CO2 Reduction

Z Zhang, J Zhu, S Chen, W Sun… - Angewandte Chemie, 2023 - Wiley Online Library
Precise design and tuning of the micro‐atomic structure of single atom catalysts (SACs) can
help efficiently adapt complex catalytic systems. Herein, we inventively found that when the …

Supported metal clusters: fabrication and application in heterogeneous catalysis

C Dong, Y Li, D Cheng, M Zhang, J Liu, YG Wang… - ACS …, 2020 - ACS Publications
Different from isolated metal atoms and large metal nanoparticles (NPs), supported metal
clusters (SMCs) possess distinct geometric and electronic structures and thus exhibit …

[PDF][PDF] Machine learning for heterogeneous catalyst design and discovery

BR Goldsmith, J Esterhuizen, JX Liu, CJ Bartel… - 2018 - deepblue.lib.umich.edu
Advances in machine learning (ML) are making a large impact in many fields, including:
artificial intelligence, 1 materials science, 2, 3 and chemical engineering. 4 Generally, ML …

Operando Electron Microscopy of Catalysts: The Missing Cornerstone in Heterogeneous Catalysis Research?

SW Chee, T Lunkenbein, R Schlögl… - Chemical …, 2023 - ACS Publications
Heterogeneous catalysis in thermal gas-phase and electrochemical liquid-phase chemical
conversion plays an important role in our modern energy landscape. However, many of the …

Approaches for understanding and controlling interfacial effects in oxide-supported metal catalysts

I Ro, J Resasco, P Christopher - ACS Catalysis, 2018 - ACS Publications
Heterogeneous supported metal catalysts are critical for a wide range of chemical
conversion technologies. While the fundamental properties of extended metal surfaces are …

Advances of atomically dispersed catalysts from single-atom to clusters in energy storage and conversion applications

Y Wang, X Cui, J Zhang, J Qiao, H Huang, J Shi… - Progress in Materials …, 2022 - Elsevier
Owing to the special structural characteristics and maximized efficiency, atomically
dispersed catalysts (ADCs) with different atom sizes ranged from the single atom to clusters …

New horizon of nanoparticle and cluster catalysis with dendrimers

K Yamamoto, T Imaoka, M Tanabe, T Kambe - Chemical reviews, 2019 - ACS Publications
Among various approaches synthesizing metal nanoparticles and tiny clusters, a template
method using dendrimers has significant advantages over other chemical approaches with …

Engineering single-atom catalysts toward biomedical applications

B Chang, L Zhang, S Wu, Z Sun, Z Cheng - Chemical Society Reviews, 2022 - pubs.rsc.org
Due to inherent structural defects, common nanocatalysts always display limited catalytic
activity and selectivity, making it practically difficult for them to replace natural enzymes in a …