Discrete transition-metal clusters with metal–metal or metal–oxygen–metal bonds represent
a new category of functional materials with numerous unusual properties. For instance, the …

Miniaturizing metallic materials from the nanoscale to the atomic scale transforms the
structures and physical properties. Among these sub-nanoscale materials, some catalysts …

Advancing the understanding of lithum nickelate complexes, here we report a family of
homoleptic organonickelate complexes obtained by reacting Ni (COD) 2 and lithium aryl …

Complexes of transition metals with heavy analogs of carbenes (tetrylenes) as ligands have
been studied now for some 40 years. The current review attempts to provide an overview …

A series of zero-valent palladium complexes featuring diphosphinometal ligands is reported.
The metalloligand in the PMP-type framework (M= LiI, CuI, ZnII) acts as a weak to medium …

The reaction mechanism of decarboxylative cross-couplings of benzoates with aryl halides
to give biaryls, which is cooperatively catalyzed by copper/palladium systems, was …

Transition-metal complexes are widely used in the physical and biological sciences. They
have essential roles in catalysis, synthesis, materials science, photophysics and …

Late transition metal complexes with metal-silicon or metal-germanium σsingle bondbond
show the chemical properties that could not be found for the complexes with metal-carbon …

The activation of Si-H bonds and/or Si-Si bonds in organosilicon compounds by transition-
metal species plays a crucial role for the production of functional organosilicon compounds …

Although discrete nano-sized compounds consisting of a monolayer sheet of multiple atoms
have attracted much attention, monolayer transition metal nanosheets are difficult to access …