Photomediated Giese reactions are at the forefront of radical chemistry, much like the
classical tin‐mediated Giese reactions were nearly forty years ago. With the global …

Conspectus Iridium (III) complexes have assumed a prominent role in the areas of
photochemistry and photophysics due to the peculiar properties of both the metal itself and …

Sulfonylated aromatics are commonplace motifs in drugs and agrochemicals. However,
methods for the direct synthesis of sulfonylated non‐classical arene bioisosteres, which …

Chemists extensively use free radical reactivity for applications in organic synthesis,
materials science, and life science. Traditionally, generating radicals requires strategies that …

The rapid exploration of sp3‐enriched chemical space is facilitated by fragment‐coupling
technologies that utilize simple and abundant alkyl precursors, among which alcohols are a …

This report details the development and implementation of a strategy to construct aryl-and
heteroaryl sulfones via Ni/photoredox dual catalysis. Using aryl sulfinate salts, the C–S bond …

We present a redox-neutral method for the photocatalytic generation of carbanions. Benzylic
carboxylates are photooxidized by single electron transfer; immediate CO2 extrusion and …

Decyanation is an important process in the synthesis of aromatic molecules in the studies of
pharmaceutical research, medical and materials sciences. In late‐stage modifications of …

The use of sulfinic acids and their salts continues to be extensively developed in organic
chemistry. This is attributable to their dual capacity for acting as nucleophilic or electrophilic …

Ketyl radicals are valuable reactive intermediates because they allow carbonyl chemistry to
be extended beyond traditional electrophilic reactivity through simple single-electron …