Creation from Confusion and Fusion in the Porphyrin World─ The Last Three Decades of N-Confused Porphyrinoid Chemistry

M Toganoh, H Furuta - Chemical Reviews, 2022‏ - ACS Publications
Confusion is a novel concept of isomerism in porphyrin chemistry, delivering a steady
stream of new chemistry since the discovery of N-confused porphyrin, a porphyrin mutant, in …

Sustainable metal complexes for organic light-emitting diodes (OLEDs)

C Bizzarri, E Spuling, DM Knoll, D Volz… - Coordination Chemistry …, 2018‏ - Elsevier
Organic light-emitting diodes (OLEDs) produced from metal complexes play an important
role in modern electroluminescent devices. While OLEDs are being used in display various …

Definition of the tetrel bond

PR Varadwaj, A Varadwaj, HM Marques… - …, 2023‏ - pubs.rsc.org
This paper proposes a definition of the term “tetrel bond” based on the evidence
documented in the current literature. It lists the donors, acceptors, as well as related …

aza-BODIPY synthesis towards vis/NIR functional chromophores based on a Schiff base forming reaction protocol using lactams and heteroaromatic amines

S Shimizu - Chemical Communications, 2019‏ - pubs.rsc.org
aza-BODIPY is a class of heteroatom-containing BODIPY analogues targeting near infrared
(NIR) chromophores and fluorophores. As a synthetic strategy towards aza-BODIPY …

Sn (IV) N-confused porphyrins as photosensitizer dyes for photodynamic therapy in the near IR region

B Babu, J Mack, T Nyokong - Dalton transactions, 2020‏ - pubs.rsc.org
The utility of Sn (IV) N-confused porphyrin (SnNCP) for use as photosensitizer dyes in
photodynamic therapy is investigated. SnNCP has an unusually high singlet oxygen …

Polyhalide-bonded metal complexes: Structural diversity in an eclectic class of compounds

SA Adonin, MN Sokolov, VP Fedin - Coordination Chemistry Reviews, 2018‏ - Elsevier
This review is focused on a special class of metal complexes where polyhalide units are
either coordinated to metal (“true polyhalide complexes”) or form specific associates with …

Photodynamic Anticancer and Antibacterial Activities of Sn(IV) N-Confused Meso-tetra(methylthiophenyl)porphyrin

S Dingiswayo, B Babu, K Burgess, J Mack, T Nyokong - Photochem, 2023‏ - mdpi.com
A Sn (IV) meso-tetra (4-methylthiolphenyl) N-confused porphyrin (4-Sn) complex was
prepared to facilitate a comparison of the photophysicochemical and singlet oxygen …

Photodynamic Antitumor and Antimicrobial Activities of Free‐Base Tetra (4‐methylthiolphenyl) chlorin and Its Tin (IV) Complex

S Dingiswayo, K Burgess, B Babu, J Mack… - …, 2022‏ - Wiley Online Library
Abstract Meso‐tetra (4‐methylthiolphenyl) chlorin (3) and its Sn (IV) complex (3‐Sn) have
been synthesized and characterized. The heavy atom effects of the Sn (IV) ion and sulfur …

Oxidation of 3‐Oxo‐N‐Confused Porphyrin with PIFA: Inner and meso Functionalizations

Y Zhang, H Liu, H He, B Zou, Z Zhai… - European Journal of …, 2023‏ - Wiley Online Library
Conjugate addition of ethanol and subsequent oxidation with [bis (trifluoroacetoxy) iodo]
benzene (PIFA) allowed for the inner ethoxylation of 3‐oxo‐N‐confused …

N‐Confused Porphyrin‐aza‐Dipyrrin Chimera: A Versatile Metal Coordination Ligand Using its Unique NH Tautomerism

M Fukuda, S Mori, H Furuta… - Chemistry–An Asian …, 2019‏ - Wiley Online Library
A novel N‐confused porphyrin (NCP) analogue bearing an external aza‐dipyrrin‐like
coordination site was synthesized by a Schiff‐base forming reaction of N‐confused …