Molybdenum and tungsten are heavy metallic elements, belonging to the sixth group of the
“d-block” of the periodic table, with electronic configurations [Kr] 4d5 5s1 and [Xe] 4f 14 5d4 …

The aerobic CO dehydrogenase from Oligotropha carboxidovorans | JBIC Journal of Biological
Inorganic Chemistry Skip to main content Springer Nature Link Account Menu Find a journal …

Constructing synthetic models of the Mo/Cu active site of aerobic carbon monoxide
dehydrogenase (CODH) has been a long-standing synthetic challenge thought to be crucial …

One-electron reduction of Cu3E L (L 3–= tris (β-diketiminate) cyclophane, and E= S, Se)
affords [Cu3E L]−, which reacts with CO2 to yield exclusively C2O42–(95% yield, TON= 24) …

Carbon monoxide (CO) pollutes the atmosphere and is toxic for respiring organisms
including man. But CO is also an energy and carbon source for phylogenetically diverse …

Sulfide and transition metals often came together in Biology. The variety of possible
structural combinations enabled living organisms to evolve an array of highly versatile metal …

Abstract (Photo) Electrochemical reduction of proton, CO 2 or N 2 is an attractive
technological approach for producing large scale of green-or low-carbon fuels like H 2 …

We review the xanthine oxidase (XO) family of pyranopterin molybdenum enzymes with a
specific emphasis on electronic structure contributions to reactivity. In addition to xanthine …

Previous density functional theory (DFT) studies have shown that the release of the
produced carbon dioxide (CO2) from an active-site cluster is a thermodynamically or …

In this study, we report the synthesis, characterization, and reactions of Cu (I) complexes of
the general form Cu (L)(LigH2)(LigH2= xanthene-based heterodinucleating ligand (E)-3-(((5 …