Abstract Singlet oxygen (1O2) has attracted great attention owing to its superior
comprehensive oxidizing performance and extensive application in dealing with ever …

We demonstrate that single-atom alloy catalysts can be made by exposing physical mixtures
of monometallic supported Cu and Pd catalysts to vinyl acetate (VA) synthesis reaction …

The controlled design of bimetallic nanoparticles (BNPs) is a key goal in tailoring their
catalytic properties. Recently, biomimetic pathways demonstrated potent control over the …

Gas phase synthesis of vinyl acetate from ethylene over Pd-Au catalyst is one of the
mainstream processes. During the synthesis of vinyl acetate, the surface C generated by the …

Vinyl acetate is one of the important chemical raw materials for the production of polyvinyl
alcohol and polyvinyl acetate, and ethylene gas phase process is one of its mainstream …

PdAu catalysts supported on both pure silica and aluminosilicates and promoted with KOAc
are the most active and selective compositions for the industrial-scale acetoxylation of …

Kinetics of heterogeneous catalytic reactions are often complicated by various factors, and
from the perspective of statistical physics the development of the corresponding models is …

Potassium-promoted, oxide-supported PdAu is catalytically active for the gas-phase
acetoxylation of ethylene to form vinyl acetate monomer (VAM), in which the potassium …

Catalytic reactions running in an adsorbed overlayer on metallic alloy nanoparticles are of
high interest in the context of applications in the chemical industry. The understanding of the …

Vinyl acetate is mainly produced by oxidative acetoxylation of ethylene over the Pd/Au
bimetallic heterogeneous catalyst. This process requires the involvement of oxygen, but the …