Redox and electrochemical water splitting catalytic properties of hydrated metal oxide modified electrodes

RL Doyle, IJ Godwin, MP Brandon… - Physical Chemistry …, 2013 - pubs.rsc.org
This paper presents a review of the redox and electrocatalytic properties of transition metal
oxide electrodes, paying particular attention to the oxygen evolution reaction. Metal oxide …

Iron-and cobalt-catalyzed C (sp 3)–H bond functionalization reactions and their application in organic synthesis

Y Liu, T You, HX Wang, Z Tang, CY Zhou… - Chemical Society …, 2020 - pubs.rsc.org
Direct C–H bond functionalization catalyzed by non-precious transition metals is an
attractive strategy in synthetic chemistry. Compared with the precious metals rhodium …

Chemo-and stereoselective CH oxidations and epoxidations/cis-dihydroxylations with H2O2, catalyzed by non-heme iron and manganese complexes

EP Talsi, KP Bryliakov - Coordination Chemistry Reviews, 2012 - Elsevier
The discovery of simple and efficient catalyst systems for the selective oxofunctionalization
of hydrocarbons is a challenging task of modern chemistry. The biomimetic approach, which …

An electrochemical impedance study of the oxygen evolution reaction at hydrous iron oxide in base

RL Doyle, MEG Lyons - Physical Chemistry Chemical Physics, 2013 - pubs.rsc.org
The oxygen evolution reaction at multi-cycled iron oxy-hydroxide films in aqueous alkaline
solution is discussed. Steady-state Tafel plot analysis and electrochemical impedance …

Green and Efficient: Iron-Catalyzed Selective Oxidation of Olefins to Carbonyls with O2

A Gonzalez-de-Castro, J **ao - Journal of the American Chemical …, 2015 - ACS Publications
A mild and operationally simple iron-catalyzed protocol for the selective aerobic oxidation of
aromatic olefins to carbonyl compounds is described. Catalyzed by a Fe (III) species bearing …

Kinetics and mechanistic aspects of the oxygen evolution reaction at hydrous iron oxide films in base

RL Doyle, MEG Lyons - Journal of The Electrochemical Society, 2013 - iopscience.iop.org
The oxygen evolution reaction at multi-cycled iron oxy-hydroxide films in aqueous alkaline
solution is discussed. The factors affecting the growth and electrocatalytic properties of the …

Formation of a Room Temperature Stable FeV(O) Complex: Reactivity Toward Unactivated C–H Bonds

M Ghosh, KK Singh, C Panda, A Weitz… - Journal of the …, 2014 - ACS Publications
An FeV (O) complex has been synthesized from equimolar solutions of (Et4N) 2 [FeIII
(Cl)(biuret-amide)] and m CPBA in CH3CN at room temperature. The FeV (O) complex has …

The oxygen evolution reaction: mechanistic concepts and catalyst design

RL Doyle, MEG Lyons - … Solar Fuel Production: From Basic Principles to …, 2016 - Springer
Fundamental aspects of the oxygen evolution reaction mediated by metal oxide catalysts are
presented. The oxygen evolution reaction is a critical bottleneck in the generation of …

Neutron cryo-crystallography captures the protonation state of ferryl heme in a peroxidase

CM Casadei, A Gumiero, CL Metcalfe, EJ Murphy… - Science, 2014 - science.org
Heme enzymes activate oxygen through formation of transient iron-oxo (ferryl) intermediates
of the heme iron. A long-standing question has been the nature of the iron-oxygen bond …

Mechanistic Insights on the ortho-Hydroxylation of Aromatic Compounds by Non-heme Iron Complex: A Computational Case Study on the Comparative Oxidative Ability of Ferric …

A Ansari, A Kaushik, G Rajaraman - Journal of the American …, 2013 - ACS Publications
ortho-Hydroxylation of aromatic compounds by non-heme Fe complexes has been
extensively studied in recent years by several research groups. The nature of the proposed …