Closed-loop recyclable polymers: from monomer and polymer design to the polymerization–depolymerization cycle

S Yang, S Du, J Zhu, S Ma - Chemical Society Reviews, 2024 - pubs.rsc.org
The extensive utilization of plastic, as a symbol of modern technological society, has
consumed enormous amounts of finite and non-renewable fossil resources and produced …

Sulfur chemistry in polymer and materials science

H Mutlu, EB Ceper, X Li, J Yang… - Macromolecular …, 2019 - Wiley Online Library
Sulfur and its functional groups are major players in an area of exciting research taking
place in modern polymer and materials science, both in academia and industry. In fact …

4-Hydroxyproline-derived sustainable polythioesters: controlled ring-opening polymerization, complete recyclability, and facile functionalization

J Yuan, W **ong, X Zhou, Y Zhang, D Shi… - Journal of the …, 2019 - ACS Publications
The sustainable production of chemically recyclable polymers presents a significant
opportunity to polymer scientists to tackle the growing environmental and energy problems …

Geminal dimethyl substitution enables controlled polymerization of penicillamine-derived β-thiolactones and reversed depolymerization

W **ong, W Chang, D Shi, L Yang, Z Tian, H Wang… - Chem, 2020 - cell.com
To access infinitely recyclable plastics, one appealing approach is to design
thermodynamically neutral systems based on dynamic covalent bond, the (de) …

Modulating polymerization thermodynamics of thiolactones through substituent and heteroatom incorporation

KA Stellmach, MKK Paul, M Xu, YL Su, L Fu… - ACS Macro …, 2022 - ACS Publications
A central challenge in the development of next-generation sustainable materials is to design
polymers that can easily revert back to their monomeric starting material through chemical …

Recent advances in the ring-opening polymerization of sulfur-containing monomers

VB Purohit, M Pięta, J Pietrasik, CM Plummer - Polymer Chemistry, 2022 - pubs.rsc.org
Inspired by the uniqueness of ring-opening polymerization and the ubiquity of sulfur-
containing heterocycles, much attention has been paid to the synthesis of sulfur-containing …

Methods for the direct synthesis of thioesters from aldehydes: a focus review

NH Jabarullah, K Jermsittiparsert… - Journal of Sulfur …, 2020 - Taylor & Francis
Direct C–H bond functionalization chemistry allows the pot-, atom-, and step-economical
and original construction of carbon–carbon and carbon-heteroatom bonds starting from …

Recyclable polythioesters and polydisulfides with near-equilibrium thermodynamics and dynamic covalent bonds

W **ong, H Lu - Science China Chemistry, 2023 - Springer
The accumulation of discarded petroleum-based plastics causes serious environmental
crises. Currently, recyclable polymers with neutrality in thermodynamics, such as polyesters …

Polythioesters Prepared by Ring‐Opening Polymerization of Cyclic Thioesters and Related Monomers

H Li, SM Guillaume… - Chemistry–An Asian …, 2022 - Wiley Online Library
Polyhydroxyalkanoates (PHAs) are biodegradable and biocompatible polyesters with a wide
range of applications; in particular, they currently stand as promising alternatives to …

Tacticity Control of Cyclic Poly (3‐Thiobutyrate) Prepared by Ring‐Opening Polymerization of Racemic β‐Thiobutyrolactone

H Li, J Ollivier, SM Guillaume… - Angewandte Chemie …, 2022 - Wiley Online Library
We report here on the ring‐opening polymerization (ROP) of racemic β‐thiobutyrolactone
(rac‐TBL), as the first chemical synthesis of poly (3‐thiobutyrolactone)(P3TB), the thioester …