Structure, properties and reactivity of polyoxometalates: a theoretical perspective

X López, JJ Carbó, C Bo, JM Poblet - Chemical Society Reviews, 2012 - pubs.rsc.org
In the thematic review dedicated to polyoxometalate (POM) chemistry published in Chemical
Reviews in 1998, no contribution was devoted to theory. This is not surprising because …

State-of-the-art advances in the structural diversities and catalytic applications of polyoxoniobate-based materials

HY Zhao, YZ Li, JW Zhao, L Wang, GY Yang - Coordination Chemistry …, 2021 - Elsevier
Polyoxoniobates (PONbs), a remarkable category of metal-oxo cluster materials, have
attracted significant attention, owing to their structural diversity and high nucleophilicity …

Polyoxoniobate chemistry in the 21st century

M Nyman - Dalton Transactions, 2011 - pubs.rsc.org
Polyoxometalate (POM) chemistry of W, Mo and V is rich and diverse; and new discoveries
are frequent and abundant. The prolificacy of this POM chemistry is attributed to rich redox …

Hetero and lacunary polyoxovanadate chemistry: Synthesis, reactivity and structural aspects

Y Hayashi - Coordination Chemistry Reviews, 2011 - Elsevier
Many synthetic methods for heteropolyoxovanadates and lacunary polyoxovanadates have
been developed in recent years. We outline various approaches used to produce new …

Structural overview and evolution paths of lacunary polyoxometalates

LL Liu, L Wang, XY ** is one of the most
effective ways. At present, atomically precise heterometallic polyoxotitanium clusters …

Decaniobate: The Fruit Fly of Niobium Polyoxometalate Chemistry

M Nyman, T Rahman, I Colliard - Accounts of Chemical Research, 2023 - ACS Publications
Conspectus Polyoxometalates (POMs, metals= V4/5+, Nb5+, Ta5+, Mo5/6+, and W5/6+) can
be described as molecular metal oxides. The V, Mo, and W-POMs (classic POMs) exhibit …

Evolution of polyoxoniobate cluster anions

RP Bontchev, M Nyman - Angewandte Chemie, 2006 - Wiley Online Library
Early transition metals such as V, Mo, and W are well known to form complex polyoxoanions
over a wide pH range,[1] for example, some exceptionally large ring-shaped oxo …

Synthesis, structural characterization, and molecular modeling of dodecaniobate Keggin chain materials

F Bonhomme, JP Larentzos, TM Alam… - Inorganic …, 2005 - ACS Publications
Four new isostructural one-dimensional dodecaniobate Keggin materials, Na12
[Ti2O2][TNb12O40]⊙ x H2O and Na10 [Nb2O2][TNb12O40]⊙ x H2O with T=(Si or Ge) …