Atomically precise colloidal metal nanoclusters and nanoparticles: fundamentals and opportunities

R **, C Zeng, M Zhou, Y Chen - Chemical reviews, 2016 - ACS Publications
Colloidal nanoparticles are being intensely pursued in current nanoscience research.
Nanochemists are often frustrated by the well-known fact that no two nanoparticles are the …

Toward active-site tailoring in heterogeneous catalysis by atomically precise metal nanoclusters with crystallographic structures

R **, G Li, S Sharma, Y Li, X Du - Chemical Reviews, 2020 - ACS Publications
Heterogeneous catalysis involves solid-state catalysts, among which metal nanoparticles
occupy an important position. Unfortunately, no two nanoparticles from conventional …

Atomically precise noble metal nanoclusters as efficient catalysts: a bridge between structure and properties

Y Du, H Sheng, D Astruc, M Zhu - Chemical reviews, 2019 - ACS Publications
Improving the knowledge of the relationship between structure and properties is
fundamental in catalysis. Recently, researchers have developed a variety of well-controlled …

Bottom-up precise synthesis of stable platinum dimers on graphene

H Yan, Y Lin, H Wu, W Zhang, Z Sun, H Cheng… - Nature …, 2017 - nature.com
Supported metal clusters containing only a few atoms are of great interest. Progress has
been made in synthesis of metal single-atom catalysts. However, precise synthesis of metal …

Au 25 (SR) 18: the captain of the great nanocluster ship

X Kang, H Chong, M Zhu - Nanoscale, 2018 - pubs.rsc.org
Noble metal nanoclusters are in the intermediate state between discrete atoms and
plasmonic nanoparticles and are of significance due to their atomically accurate structures …

The role and fate of cap** ligands in colloidally prepared metal nanoparticle catalysts

LM Rossi, JL Fiorio, MAS Garcia, CP Ferraz - Dalton Transactions, 2018 - pubs.rsc.org
Metal nanoparticles have received intense scientific attention in the field of catalysis. Precise
engineering of nanomaterials' size, shape and surface composition, including adsorbed …

Shining photocatalysis by gold-based nanomaterials

H Zhu, X Yuan, Q Yao, J **e - Nano Energy, 2021 - Elsevier
As an environmentally friendly technology, photocatalysis has been widely used in many
fields. Currently, the drawbacks of pristine semiconductors as traditional photocatalysts …

Roles of thiolate ligands in the synthesis, properties and catalytic application of gold nanoclusters

RR Nasaruddin, T Chen, N Yan, J **e - Coordination Chemistry Reviews, 2018 - Elsevier
Abstract Ultrasmall (< 2 nm) ligand-protected metal nanoclusters (NCs) have been an
emerging class of functional materials with rich coordination chemistry, finding increasing …

Engineering functional metal materials at the atomic level

Q Yao, X Yuan, T Chen, DT Leong, J **e - Advanced Materials, 2018 - Wiley Online Library
With continuous research efforts devoted into synthesis and characterization chemistry of
functional nanomaterials in the past decades, the development of metal materials is …

Recent advances in the synthesis and catalytic applications of ligand-protected, atomically precise metal nanoclusters

J Fang, B Zhang, Q Yao, Y Yang, J **e… - Coordination Chemistry …, 2016 - Elsevier
Due to their excellent catalytic properties under mild reaction conditions, well-defined,
nanosized noble metal catalysts have potential applications in the manufacture of fine …