Recent Advances in the Chemical Synthesis of C-Glycosides

Y Yang, B Yu - Chemical reviews, 2017 - ACS Publications
Advances in the chemical synthesis of C-pyranosides/furanosides are summarized, covering
the literature from 2000 to 2016. The majority of the methods take advantage of the …

Efficient synthesis of chirally enriched 1H-Imidazo [1, 2-b] pyrazole-and 4H-Imidazo [1, 2-b][1, 2, 4] triazole-based bioactive glycohybrids

VK Mishra, G Tiwari, A Khanna, R Tyagi, R Sagar - Synthesis, 2024 - thieme-connect.com
Carbohydrates, traditionally known for their energy-providing role, have gained significant
attention in drug discovery due to their diverse bioactivities and stereodiversity. However …

Development of Routes for the Stereoselective Preparation of β-Aryl-C-glycosides via C-1 Aryl Enones

AK Singh, VK Kanaujiya, V Tiwari, S Sabiah… - Organic …, 2020 - ACS Publications
A wide range of enones derived from d-glucal, d-galactal, l-rhamnal, d-rhamnal, and l-
arabinal underwent Heck-coupling with various arylboronic acids bearing electron-donating …

Copper-Mediated Direct Functionalization of Unsaturated C–C Bonds with Ethyl Bromo (difluoro) acetate: A Straightforward Access to Highly Valuable …

MC Belhomme, D Dru, HY **ong, D Cahard… - …, 2014 - thieme-connect.com
A copper-mediated fluorofunctionalization of alkenes and alkynes has been developed. This
method provides ready access to trisubstituted difluoromethylated olefins (from …

Transition metals in organic synthesis: Highlights for the year 2005

BCG Söderberg - Coordination Chemistry Reviews, 2008 - Elsevier
A review with 1627 references to transition metal catalyzed or mediated reactions and
functional group preparations.

TEMPO-Catalyzed Oxidation of 3-O-Benzylated/Silylated Glycals to the Corresponding Enones Using a PIFA–Water Reagent System

A Chennaiah, AK Verma… - The Journal of Organic …, 2018 - ACS Publications
A simple, highly efficient and regiospecific method for the direct conversion of 3-O-
benzylated as well as silylated glycals into the corresponding enones has been developed …

(S,S)-(+)-Pseudoephedrine as Chiral Auxiliary in Asymmetric Conjugate Addition and Tandem Conjugate Addition/α-Alkylation Reactions

E Reyes, JL Vicario, L Carrillo, D Badia… - The Journal of …, 2006 - ACS Publications
Organolithium reagents undergo highly regio-and diastereoselective 1, 4-addition to (S, S)-
(+)-pseudoephedrine enamides furnishing the corresponding β-alkyl-substituted adducts in …

Base‐Induced Annulation of Glycal‐Derived α‐iodopyranone with 2‐Aminopyrimidinones: Access to Chiral Imidazopyrimidinones

VK Mishra, G Tiwari, A Khanna… - European Journal of …, 2024 - Wiley Online Library
A simple, environmentally benign and catalyst‐free method for the synthesis of chirally
enriched imidazo [1, 2‐a] pyrimidinone glycohybrids has been successfully developed. The …

Base Induced Chiral Substituted Furans and Imidazoles from Carbohydrate-Derived 2-Haloenones

K Mal, I Das - The Journal of Organic Chemistry, 2016 - ACS Publications
Chiral substituted furans and imidazoles are key intermediates to access biologically
important molecules. We describe herein a catalyst/ligand free cascade Michael-type …

Pyranose glycals in the generation of skeletal diversity

AM Gómez, F Lobo, JC López - 2015 - books.rsc.org
The presence of an unsaturation in a pyranose derivative provides a powerful handle for the
creation of new compounds displaying a variety of molecular skeletons. This contribution …