Discovery of the N–NHC coupling process under the conditions of Pd/NHC-and Ni/NHC-catalyzed buchwald–hartwig amination
VM Chernyshev, OV Khazipov, MA Shevchenko… - …, 2022 - ACS Publications
Complexes of palladium and nickel with N-heterocyclic carbene ligands (M/NHC, M= Pd, Ni)
are widely used as effective catalysts for various amination reactions. A previously …
are widely used as effective catalysts for various amination reactions. A previously …
Tailor-Made POLITAG-Pd0 Catalyst for the Low-Loading Mizoroki–Heck Reaction in γ-Valerolactone as a Safe Reaction Medium
In this contribution, we have reported our study on the fine-tuned design and synthesis of
new POLITAGs-Pd0 (POLymeric Ionic TAG) catalytic systems with the intention of defining …
new POLITAGs-Pd0 (POLymeric Ionic TAG) catalytic systems with the intention of defining …
Nitron-derivative-based palladium carbene complexes: structural characterization, theoretical calculations, and catalytic applications in the Mizoroki–Heck coupling …
MY Lee, CH Liao, HY Hung, JY Lee, HM Lee - RSC advances, 2023 - pubs.rsc.org
New palladium (0) and palladium (II) complexes with N-heterocyclic carbene (NHC) ligands
derived from nitron and its derivatives were synthesized. The structures of most of these …
derived from nitron and its derivatives were synthesized. The structures of most of these …
Selective Buchwald–Hartwig arylation of C-amino-1, 2, 4-triazoles and other coordinating aminoheterocycles enabled by bulky NHC ligands and TPEDO activator
AV Astakhov, AY Chernenko, VV Kutyrev… - Inorganic Chemistry …, 2023 - pubs.rsc.org
C-Amino-1, 2, 4-triazoles are challenging polynitrogen substrates for metal-catalyzed
arylation due to their multidentate character, enhanced coordinating ability and decreased …
arylation due to their multidentate character, enhanced coordinating ability and decreased …
Synthesis and a combined experimental/theoretical structural study of a comprehensive set of Pd/NHC complexes with o-, m-, and p-halogen-substituted aryl groups …
RO Pankov, DO Prima, AY Kostyukovich… - Dalton …, 2023 - pubs.rsc.org
Pd/NHC complexes (NHCs–N-heterocyclic carbenes) with electron-withdrawing halogen
groups were prepared by develo** an optimized synthetic procedure to access …
groups were prepared by develo** an optimized synthetic procedure to access …
Post-Modification of Octahedral Chiral-at-Metal Cobalt (III) Complexes by Suzuki–Miyaura Cross-Coupling and Evaluation of Their Catalytic Activity
OV Khromova, MA Emelyanov, NV Stoletova… - …, 2023 - ACS Publications
A family of well-defined Λ-and Δ-configured octahedral cationic chiral-at-cobalt catalysts
were expanded through a straightforward postcomplexation of the bromine-functionalized …
were expanded through a straightforward postcomplexation of the bromine-functionalized …
Dimroth rearrangement “thiadiazole-triazole”: synthesis and exploration of 3-sulfanyl-1, 2, 4-triazolium salts as NHC-proligands
DV Pasyukov, AY Chernenko, IV Lavrentev… - Russian Chemical …, 2022 - Springer
Abstract The reaction of 1, 4-disubstituted thiosemicarbazides with N, N-dimethylformamide
dimethyl acetal afforded 1, 4-disubstituted 1, 2, 4-triazolium-3-thiolates. Heating of the …
dimethyl acetal afforded 1, 4-disubstituted 1, 2, 4-triazolium-3-thiolates. Heating of the …
Base‐Ionizable Anionic NHC Ligands in Pd‐catalyzed Reactions of Aryl Chlorides
AY Chernenko, VA Baydikova, VV Kutyrev… - …, 2024 - Wiley Online Library
Aryl chlorides, due to their affordability and accessibility, are preferred reagents in Pd‐
catalyzed arylation reactions. However, the reactivity of aryl chlorides is often lower than that …
catalyzed arylation reactions. However, the reactivity of aryl chlorides is often lower than that …
The bulky Pd-PEPPSI-embedded conjugated microporous polymer-catalyzed Suzuki–Miyaura cross-coupling of aryl chlorides and arylboronic acids
CA Wang, W Zhao, YW Li, YF Han, JP Zhang, Q Li… - Polymer …, 2022 - pubs.rsc.org
Through a post-synthesis method, a type of bulky N-heterocyclic carbene (NHC)
functionalized conjugated microporous polymer supporting a palladium-based molecular …
functionalized conjugated microporous polymer supporting a palladium-based molecular …
PEPPSI-Type Pd(II)—NHC Complexes on the Base of p-tert-Butylthiacalix[4]arene: Synthesis and Catalytic Activities
B Gafiatullin, A Akchurina, A Fedoseeva, E Sultanova… - Inorganics, 2023 - mdpi.com
The creation of effective catalytic systems for cross-coupling reactions, reduction, etc.,
capable of working in water-organic or pure aqueous media is in great demand. The article …
capable of working in water-organic or pure aqueous media is in great demand. The article …