Realizing viable electrocatalytic processes for energy conversion/storage strongly relies on
an atomic-level understanding of dynamic configurations on catalyst-electrolyte interface. X …

Many coordination complexes and organometallic compounds with the 4d6 and 5d6
valence electron configurations have outstanding photophysical and photochemical …

Electrons are the workhorses of solar energy conversion. Conversion of the energy of light to
electricity in photovoltaics, or to energy-rich molecules (solar fuel) through photocatalytic …

Continual advancements in the development of synchrotron radiation sources have resulted
in X-ray based spectroscopic techniques capable of probing the electronic and structural …

The scarcity of 2 nd and 3 rd row transition metals such as ruthenium, iridium, rhodium and
osmium, coupled with a global desire for sustainable chemistry has led to the resurgence of …

The metal centres in metalloenzymes and molecular catalysts are responsible for the
rearrangement of atoms and electrons during complex chemical reactions, and they enable …

The iron carbene complex [FeII (btz) 3](PF6) 2 (where btz= 3, 3′-dimethyl-1, 1′-bis (p-tolyl)-
4, 4′-bis (1, 2, 3-triazol-5-ylidene)) has been synthesized, isolated, and characterized as a …

The ability of electronic devices to act as switches makes digital information processing
possible. Succeeding graphene, emerging inorganic 2D materials (i2DMs) have been …

Examples of Fe complexes with long-lived (≥ 1 ns) charge-transfer states are limited to
pseudo-octahedral geometries with strong σ-donor chelates. Alternative strategies based on …

There is a long-standing interest in iron (II) complexes that emit from metal-to-ligand charge
transfer (MLCT) excited states, analogous to ruthenium (II) polypyridines. The 3d6 electrons …