Probing cellulose structures with vibrational spectroscopy
This paper reviews principles, data interpretations, and applications of vibrational
spectroscopic methods used for analysis of cellulose in the isolated state and in plant cell …
spectroscopic methods used for analysis of cellulose in the isolated state and in plant cell …
Biological macromolecules at interfaces probed by chiral vibrational sum frequency generation spectroscopy
1. INTRODUCTION A fundamental understanding of chiral biomacromolecules at aqueous
interfaces is critical to studying a host of important phenomena in modern biology, chemistry …
interfaces is critical to studying a host of important phenomena in modern biology, chemistry …
Charge transfer across C–H⋅⋅⋅ O hydrogen bonds stabilizes oil droplets in water
The hydrophobic–water interface plays a key role in biological interactions. However, both
the hydrophobic–water interfacial molecular structure and the origin of the negative zeta …
the hydrophobic–water interfacial molecular structure and the origin of the negative zeta …
Electrolytes induce long-range orientational order and free energy changes in the H-bond network of bulk water
Electrolytes interact with water in many ways: changing dipole orientation, inducing charge
transfer, and distorting the hydrogen-bond network in the bulk and at interfaces. Numerous …
transfer, and distorting the hydrogen-bond network in the bulk and at interfaces. Numerous …
The orientation and charge of water at the hydrophobic oil droplet–water interface
R Vácha, SW Rick, P Jungwirth… - Journal of the …, 2011 - ACS Publications
We established the charge and structure of the oil/water interface by combining ζ-potential
measurements, sum frequency scattering (SFS) and molecular dynamics simulations. The …
measurements, sum frequency scattering (SFS) and molecular dynamics simulations. The …
Nonlinear light scattering and spectroscopy of particles and droplets in liquids
Nano-and microparticles have optical, structural, and chemical properties that differ from
both their building blocks and the bulk materials themselves. These different physical and …
both their building blocks and the bulk materials themselves. These different physical and …
Origin of optical second-harmonic generation in spherical gold nanoparticles: Local surface and nonlocal bulk contributions
The second-harmonic generation of 150 nm spherical gold nanoparticles is investigated
both experimentally and theoretically. We demonstrate that the interference effects between …
both experimentally and theoretically. We demonstrate that the interference effects between …
Ultrafast surface vibrational dynamics
H Arnolds, M Bonn - Surface Science Reports, 2010 - Elsevier
Surface vibrational spectroscopy has developed rapidly over the past decades, thanks to the
advent of ultrashort tunable laser pulses in the mid-infrared range. In particular, femtosecond …
advent of ultrashort tunable laser pulses in the mid-infrared range. In particular, femtosecond …
Nonlinear Mie theory for second-harmonic and sum-frequency scattering
We present a theory for second-order nonlinear light scattering from spherical particles
using source waves of arbitrary frequency and direction based on a combination of linear …
using source waves of arbitrary frequency and direction based on a combination of linear …
The interfacial tension of nanoscopic oil droplets in water is hardly affected by SDS surfactant
Surfactants such as sodium dodecylsulfate (SDS) can reduce the interfacial tension between
bulk water and bulk n-hexadecane by 42 mN/m. Although reduction of interfacial tension …
bulk water and bulk n-hexadecane by 42 mN/m. Although reduction of interfacial tension …