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Controlling a chemical coupling reaction on a surface: tools and strategies for on-surface synthesis
On-surface synthesis is appearing as an extremely promising research field aimed at
creating new organic materials. A large number of chemical reactions have been …
creating new organic materials. A large number of chemical reactions have been …
Computational approach to molecular catalysis by 3d transition metals: challenges and opportunities
Computational chemistry provides a versatile toolbox for studying mechanistic details of
catalytic reactions and holds promise to deliver practical strategies to enable the rational in …
catalytic reactions and holds promise to deliver practical strategies to enable the rational in …
Surface-catalyzed C–C covalent coupling strategies toward the synthesis of low-dimensional carbon-based nanostructures
Conspectus Carbon-based nanostructures have attracted tremendous interest because of
their versatile and tunable properties, which depend on the bonding type of the constituting …
their versatile and tunable properties, which depend on the bonding type of the constituting …
Confined on-surface organic synthesis: strategies and mechanisms
On-surface synthesis has been one of the hottest research fields in surface science in the
last decade, owing to its great potential for bottom-up synthesis of functional molecules and …
last decade, owing to its great potential for bottom-up synthesis of functional molecules and …
Cobalt-Catalyzed C(sp2)–CN Bond Activation: Cross-Electrophile Coupling for Biaryl Formation and Mechanistic Insight
C Dorval, M Tricoire, JM Begouin, V Gandon… - ACS …, 2020 - ACS Publications
Herein, we report a cross-electrophile coupling of benzonitrile derivatives and aryl halides
with a simple cobalt-based catalytic system under mild conditions to form biaryl compounds …
with a simple cobalt-based catalytic system under mild conditions to form biaryl compounds …
Steering surface reaction dynamics with a self‐assembly strategy: Ullmann coupling on metal surfaces
X Zhou, C Wang, Y Zhang, F Cheng, Y He… - Angewandte …, 2017 - Wiley Online Library
Ullmann coupling of 4‐bromobiphenyl thermally catalyzed on Ag (111), Cu (111), and Cu
(100) surfaces was scrutinized by scanning tunneling microscopy as well as theoretical …
(100) surfaces was scrutinized by scanning tunneling microscopy as well as theoretical …
Interfacial electric fields catalyze Ullmann coupling reactions on gold surfaces
The electric fields created at solid–liquid interfaces are important in heterogeneous
catalysis. Here we describe the Ullmann coupling of aryl iodides on rough gold surfaces …
catalysis. Here we describe the Ullmann coupling of aryl iodides on rough gold surfaces …
On-surface synthesis approach to preparing one-dimensional organometallic and poly-p-phenylene chains
X Zhou, F Bebensee, Q Shen, R Bebensee… - Materials Chemistry …, 2017 - pubs.rsc.org
On-surface Ullmann coupling reactions of dibromo-biphenyl and diiodo-biphenyl molecules
on Ag (111), Cu (111), Au (111) and Au (100) and by deposited extrinsic Ag and Ni atoms …
on Ag (111), Cu (111), Au (111) and Au (100) and by deposited extrinsic Ag and Ni atoms …
Aryl-aryl bond formation by Ullmann reaction: from mechanistic aspects to catalyst
J Jiang, L Du, Y Ding - Mini-Reviews in Organic Chemistry, 2020 - ingentaconnect.com
Aryl-aryl bond formation is one of the most important tools in modern organic synthesis.
Therefore, there is a high level of interest to develop green, effective reaction system to …
Therefore, there is a high level of interest to develop green, effective reaction system to …
Single-molecule insight into Wurtz reactions on metal surfaces
Q Sun, L Cai, Y Ding, H Ma, C Yuan… - Physical Chemistry …, 2016 - pubs.rsc.org
Wurtz reactions feature the dehalogenated coupling of alkyl halides. In comparison to their
widely investigated counterparts, Ullmann reactions, Wurtz reactions have however been …
widely investigated counterparts, Ullmann reactions, Wurtz reactions have however been …