Controlling a chemical coupling reaction on a surface: tools and strategies for on-surface synthesis

S Clair, DG de Oteyza - Chemical reviews, 2019 - ACS Publications
On-surface synthesis is appearing as an extremely promising research field aimed at
creating new organic materials. A large number of chemical reactions have been …

Computational approach to molecular catalysis by 3d transition metals: challenges and opportunities

KD Vogiatzis, MV Polynski, JK Kirkland… - Chemical …, 2018 - ACS Publications
Computational chemistry provides a versatile toolbox for studying mechanistic details of
catalytic reactions and holds promise to deliver practical strategies to enable the rational in …

Surface-catalyzed C–C covalent coupling strategies toward the synthesis of low-dimensional carbon-based nanostructures

Q Fan, JM Gottfried, J Zhu - Accounts of chemical research, 2015 - ACS Publications
Conspectus Carbon-based nanostructures have attracted tremendous interest because of
their versatile and tunable properties, which depend on the bonding type of the constituting …

Confined on-surface organic synthesis: strategies and mechanisms

T Wang, J Zhu - Surface Science Reports, 2019 - Elsevier
On-surface synthesis has been one of the hottest research fields in surface science in the
last decade, owing to its great potential for bottom-up synthesis of functional molecules and …

Cobalt-Catalyzed C(sp2)–CN Bond Activation: Cross-Electrophile Coupling for Biaryl Formation and Mechanistic Insight

C Dorval, M Tricoire, JM Begouin, V Gandon… - ACS …, 2020 - ACS Publications
Herein, we report a cross-electrophile coupling of benzonitrile derivatives and aryl halides
with a simple cobalt-based catalytic system under mild conditions to form biaryl compounds …

Steering surface reaction dynamics with a self‐assembly strategy: Ullmann coupling on metal surfaces

X Zhou, C Wang, Y Zhang, F Cheng, Y He… - Angewandte …, 2017 - Wiley Online Library
Ullmann coupling of 4‐bromobiphenyl thermally catalyzed on Ag (111), Cu (111), and Cu
(100) surfaces was scrutinized by scanning tunneling microscopy as well as theoretical …

Interfacial electric fields catalyze Ullmann coupling reactions on gold surfaces

IB Stone, RL Starr, N Hoffmann, X Wang, AM Evans… - Chemical …, 2022 - pubs.rsc.org
The electric fields created at solid–liquid interfaces are important in heterogeneous
catalysis. Here we describe the Ullmann coupling of aryl iodides on rough gold surfaces …

On-surface synthesis approach to preparing one-dimensional organometallic and poly-p-phenylene chains

X Zhou, F Bebensee, Q Shen, R Bebensee… - Materials Chemistry …, 2017 - pubs.rsc.org
On-surface Ullmann coupling reactions of dibromo-biphenyl and diiodo-biphenyl molecules
on Ag (111), Cu (111), Au (111) and Au (100) and by deposited extrinsic Ag and Ni atoms …

Aryl-aryl bond formation by Ullmann reaction: from mechanistic aspects to catalyst

J Jiang, L Du, Y Ding - Mini-Reviews in Organic Chemistry, 2020 - ingentaconnect.com
Aryl-aryl bond formation is one of the most important tools in modern organic synthesis.
Therefore, there is a high level of interest to develop green, effective reaction system to …

Single-molecule insight into Wurtz reactions on metal surfaces

Q Sun, L Cai, Y Ding, H Ma, C Yuan… - Physical Chemistry …, 2016 - pubs.rsc.org
Wurtz reactions feature the dehalogenated coupling of alkyl halides. In comparison to their
widely investigated counterparts, Ullmann reactions, Wurtz reactions have however been …