Biobased vitrimers: Towards sustainable and adaptable performing polymer materials

MA Lucherelli, A Duval, L Avérous - Progress in Polymer Science, 2022 - Elsevier
In the last decades, Covalent Adaptable Networks (CAN) appeared as an innovative
polymer family, able to bridge the gap between thermoplastics and thermosets. CAN rely on …

Vitrimers: Current research trends and their emerging applications

J Zheng, ZM Png, SH Ng, GX Tham, E Ye, SS Goh… - Materials Today, 2021 - Elsevier
The development of recyclable plastics is a key research focus in today's world due to their
environmental issues, and non-renewability concerns. Recently, vitrimeric materials have …

Strong and tough supramolecular covalent adaptable networks with room‐temperature closed‐loop recyclability

Z Zhang, D Lei, C Zhang, Z Wang, Y **… - Advanced …, 2023 - Wiley Online Library
Abstract Development of closed‐loop chemically recyclable plastics (CCRPs) that can be
widely used in daily life can be a fundamental solution to the global plastic waste crisis …

Vitrimers: directing chemical reactivity to control material properties

M Guerre, C Taplan, JM Winne, FE Du Prez - Chemical science, 2020 - pubs.rsc.org
The development of more sustainable materials with a prolonged useful lifetime is a key
requirement for a transition towards a more circular economy. However, polymer materials …

Adaptable crosslinks in polymeric materials: resolving the intersection of thermoplastics and thermosets

GM Scheutz, JJ Lessard, MB Sims… - Journal of the American …, 2019 - ACS Publications
The classical division of polymeric materials into thermoplastics and thermosets based on
covalent network structure often implies that these categories are distinct and irreconcilable …

Biobased covalent adaptable networks: towards better sustainability of thermosets

XL Zhao, PX Tian, YD Li, JB Zeng - Green Chemistry, 2022 - pubs.rsc.org
Thermosets have many advantages such as excellent mechanical properties, dimensional
stability, and chemical and environmental resistance, but suffer from unsustainability …

Evolution of self-healing elastomers, from extrinsic to combined intrinsic mechanisms: A review

S Utrera-Barrios, R Verdejo, MA López-Manchado… - Materials …, 2020 - pubs.rsc.org
The evolution of self-healing polymers has resulted in a myriad of healing designs that have
given way to complex systems capable of supporting multiple cycles, among other features …

Synergistic dual dynamic bonds in covalent adaptable networks

J Zhao, Z Zhang, C Wang, X Yan - CCS Chemistry, 2024 - chinesechemsoc.org
Covalent adaptable networks (CANs), comprising polymer networks crosslinked by dynamic
covalent bonds (DCBs), have garnered considerable attention as sustainable materials …

Reconstruction of cellulose intermolecular interactions from hydrogen bonds to dynamic covalent networks enables a thermo-processable cellulosic plastic with …

Z Su, L Yu, L Cui, G Zhou, X Zhang, X Qiu, C Chen… - ACS …, 2023 - ACS Publications
Its excellent renewability and biodegradability make cellulose an attractive resource to
prepare fossil-based plastic alternatives. However, cellulose itself exhibits strong …

High-performance recyclable and malleable epoxy resin with vanillin-based hyperbranched epoxy resin containing dual dynamic bonds

Y Hao, L Zhong, T Li, J Zhang… - … Sustainable Chemistry & …, 2023 - ACS Publications
Dynamic covalent polymer networks represent new opportunities in the design of
sustainable epoxy resins due to their excellent malleability and reprocessability; however …