Simulating coherent multidimensional spectroscopy of nonadiabatic molecular processes: From the infrared to the x-ray regime

M Kowalewski, BP Fingerhut, KE Dorfman… - Chemical …, 2017 - ACS Publications
Crossings of electronic potential energy surfaces in nuclear configuration space, known as
conical intersections, determine the rates and outcomes of a large class of photochemical …

Classical and quantum light-induced non-adiabaticity in molecular systems

C Fábri, A Csehi, GJ Halász, LS Cederbaum… - AVS Quantum …, 2024 - pubs.aip.org
The exchange of energy between electronic and nuclear motion is the origin of non-
adiabaticity and plays an important role in many molecular phenomena and processes …

Conical intersections induced by quantum light: Field-dressed spectra from the weak to the ultrastrong coupling regimes

T Szidarovszky, GJ Halász, AG Császár… - The Journal of …, 2018 - ACS Publications
In classical laser fields with frequencies resonant with the electronic excitation in molecules,
it is by now known that conical intersections are induced by the field and are called light …

Competition between collective and individual conical intersection dynamics in an optical cavity

A Csehi, O Vendrell, GJ Halász… - New Journal of Physics, 2022 - iopscience.iop.org
Light-induced nonadiabatic phenomena arise when molecules or molecular ensembles are
exposed to resonant external electromagnetic fields. The latter can either be classical laser …

Direct signature of light-induced conical intersections in diatomics

GJ Halász, Á Vibók, LS Cederbaum - The Journal of Physical …, 2015 - ACS Publications
Nonadiabatic effects are ubiquitous in physics, chemistry, and biology. They are strongly
amplified by conical intersections (CIs), which are degeneracies between electronic states of …

Control of 1, 3-cyclohexadiene photoisomerization using light-induced conical intersections

J Kim, H Tao, JL White, VS Petrovic… - The Journal of …, 2012 - ACS Publications
We have studied the photoinduced isomerization from 1, 3-cyclohexadiene to 1, 3, 5-
hexatriene in the presence of an intense ultrafast laser pulse. We find that the laser field …

Ultrafast dynamics in the vicinity of quantum light-induced conical intersections

A Csehi, M Kowalewski, GJ Halász… - New Journal of …, 2019 - iopscience.iop.org
Nonadiabatic effects appear due to avoided crossings or conical intersections (CIs) that are
either intrinsic properties in field-free space or induced by a classical laser field in a …

Light-induced conical intersections: Topological phase, wave packet dynamics, and molecular alignment

GJ Halász, M Šindelka, N Moiseyev… - The Journal of …, 2012 - ACS Publications
In previous publications (J. Phys. B: At., Mol. Opt. Phys. 2008, 41, 221001; J. Phys. B: At.,
Mol. Opt. Phys. 2011, 44, 045603) a novel and physically interesting phenomenon was …

Polariton induced conical intersection and berry phase

MH Farag, A Mandal, P Huo - Physical Chemistry Chemical Physics, 2021 - pubs.rsc.org
We investigate the Polariton induced conical intersection (PICI) created from coupling a
diatomic molecule with the quantized photon mode inside an optical cavity, and the …

Strong field laser control of photochemistry

IR Sola, J González-Vázquez, R de Nalda… - Physical Chemistry …, 2015 - pubs.rsc.org
Strong ultrashort laser pulses have opened new avenues for the manipulation of
photochemical processes like photoisomerization or photodissociation. The presence of …