Polyethylene glycol (PEG) as a green solvent for carbon–carbon bond formation reactions

M Vafaeezadeh, MM Hashemi - Journal of Molecular Liquids, 2015 - Elsevier
In recent years, polyethylene glycol (PEG) has attracted special attention as a green and
inexpensive solvent in various chemical transformations. The current critical review deals …

Recent synthetic developments and applications of the ullmann reaction. A review

H Lin, D Sun - Organic preparations and procedures international, 2013 - Taylor & Francis
The last century represents an exciting era for the chemical evolution of transition-metal
catalyzed reactions, 1–3 and among these, the chemistry of palladium, 4–6 ruthenium, 7–10 …

Synthesis of Cu2O Nanocrystals from Cubic to Rhombic Dodecahedral Structures and Their Comparative Photocatalytic Activity

WC Huang, LM Lyu, YC Yang… - Journal of the American …, 2012 - ACS Publications
In this study, a new series of Cu2O nanocrystals with systematic shape evolution from cubic
to face-raised cubic, edge-and corner-truncated octahedral, all-corner-truncated rhombic …

Transition-Metal-Free O-, S-, and N-Arylation of Alcohols, Thiols, Amides, Amines, and Related Heterocycles

R Cano, DJ Ramón, M Yus - The Journal of Organic Chemistry, 2011 - ACS Publications
A new protocol for the Ullmann-type arylation process of different aromatic heterocycles
without any transition-metal catalyst, implying the use of a combination of an excess of …

Recent green synthetic approaches toward Ullmann reaction: A review

R Akhtar, AF Zahoor, M Irfan, TH Bokhari, A ul Haq - Chemical Papers, 2022 - Springer
The traditional Ullmann reaction which represents the copper-catalyzed coupling between
two aryl halides to build a C–C bond was first reported in 1901. Over the time, this reaction …

Poly (ethylene glycol) as reaction medium for mild Mizoroki–Heck reaction in a ball-mill

V Declerck, E Colacino, X Bantreil, J Martinez… - Chemical …, 2012 - pubs.rsc.org
Phosphine-free palladium-catalyzed Mizoroki–Heck reaction was performed using ball-
milling in polyethylene glycol under mild conditions. Good to excellent yields of coupling …

Sustainable strategies of C–N bond formation via Ullmann coupling employing earth abundant copper catalyst

G Yashwantrao, S Saha - Tetrahedron, 2021 - Elsevier
N-arylation reaction has become one of the key strategies in organic synthesis to access
several molecules of biological, agrochemical, and medicinal importance. The century-old …

PEG as an alternative reaction medium in metal-mediated transformations

E Colacino, J Martinez, F Lamaty, LS Patrikeeva… - Coordination Chemistry …, 2012 - Elsevier
Poly (ethylene glycol) s (PEGs) are an interesting environment-friendly alternative to
classical solvents. Their combination with metals and metallic salts provides powerful …

Triazine‐based mesoporous covalent imine polymers as solid supports for copper‐mediated Chan–Lam cross‐coupling N‐arylation reactions

P Puthiaraj, K Pitchumani - Chemistry–A European Journal, 2014 - Wiley Online Library
The synthesis of a novel mesoporous covalent imine polymeric (MCIPs) material, involving
simple Schiff‐base chemistry, is reported. This highly functionalised nitrogen‐rich material …

Continuous flow coupling and decarboxylation reactions promoted by copper tubing

Y Zhang, TF Jamison, S Patel, N Mainolfi - Organic Letters, 2011 - ACS Publications
A convenient and efficient flow method for Ullmann condensations, Sonogashira couplings,
and decarboxylation reactions using a commercially available copper tube flow reactor …