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Photobiocatalytic strategies for organic synthesis
MA Emmanuel, SG Bender, C Bilodeau… - Chemical …, 2023 - ACS Publications
Biocatalysis has revolutionized chemical synthesis, providing sustainable methods for
preparing various organic molecules. In enzyme-mediated organic synthesis, most reactions …
preparing various organic molecules. In enzyme-mediated organic synthesis, most reactions …
Catalytic strategies and mechanism analysis orbiting the center of critical intermediates in lignin depolymerization
Lignin, as a precious resource given to mankind by nature with abundant functional aromatic
structures, has drawn much attention in the recent decade from academia to industry …
structures, has drawn much attention in the recent decade from academia to industry …
Multiple roles of dissolved organic matter in advanced oxidation processes
Advanced oxidation processes (AOPs) can degrade a wide range of trace organic
contaminants (TrOCs) to improve the quality of potable water or discharged wastewater …
contaminants (TrOCs) to improve the quality of potable water or discharged wastewater …
Photocatalytic phosphine-mediated water activation for radical hydrogenation
The chemical activation of water would allow this earth-abundant resource to be transferred
into value-added compounds, and is a topic of keen interest in energy research,. Here, we …
into value-added compounds, and is a topic of keen interest in energy research,. Here, we …
Free energies of proton-coupled electron transfer reagents and their applications
RG Agarwal, SC Coste, BD Groff, AM Heuer… - Chemical …, 2021 - ACS Publications
We present an update and revision to our 2010 review on the topic of proton-coupled
electron transfer (PCET) reagent thermochemistry. Over the past decade, the data and …
electron transfer (PCET) reagent thermochemistry. Over the past decade, the data and …
Nitrogen-Centered Radicals in Functionalization of sp2 Systems: Generation, Reactivity, and Applications in Synthesis
C Pratley, S Fenner, JA Murphy - Chemical Reviews, 2022 - ACS Publications
The chemistry of nitrogen-centered radicals (NCRs) has plentiful applications in organic
synthesis, and they continue to expand as our understanding of these reactive species …
synthesis, and they continue to expand as our understanding of these reactive species …
Alkoxy radicals see the light: new paradigms of photochemical synthesis
Alkoxy radicals are highly reactive species that have long been recognized as versatile
intermediates in organic synthesis. However, their development has long been impeded due …
intermediates in organic synthesis. However, their development has long been impeded due …
Photochemical and electrochemical applications of proton-coupled electron transfer in organic synthesis
We present here a review of the photochemical and electrochemical applications of multi-
site proton-coupled electron transfer (MS-PCET) in organic synthesis. MS-PCETs are redox …
site proton-coupled electron transfer (MS-PCET) in organic synthesis. MS-PCETs are redox …
[HTML][HTML] Recent advances in visible light-activated radical coupling reactions triggered by (i) ruthenium,(ii) iridium and (iii) organic photoredox agents
Photoredox chemistry with organic or transition metal agents has been reviewed in earlier
years, but such is the pace of progress that we will overlap very little with earlier …
years, but such is the pace of progress that we will overlap very little with earlier …
Strategies to generate nitrogen-centered radicals that may rely on photoredox catalysis: development in reaction methodology and applications in organic synthesis
For more than 70 years, nitrogen-centered radicals have been recognized as potent
synthetic intermediates. This review is a survey designed for use by chemists engaged in …
synthetic intermediates. This review is a survey designed for use by chemists engaged in …