Activation of dinitrogen by polynuclear metal complexes
Activation of dinitrogen plays an important role in daily anthropogenic life, and the processes
by which this fixation occurs have been a longstanding and significant research focus within …
by which this fixation occurs have been a longstanding and significant research focus within …
Cooperative catalysis with first‐row late transition metals
JI van der Vlugt - European Journal of Inorganic Chemistry, 2012 - Wiley Online Library
Cooperative catalysis with first‐row transition metals holds much promise for future
developments regarding sustainable, selective transformations, including eg alkenes …
developments regarding sustainable, selective transformations, including eg alkenes …
Boryl-Mediated Reversible H2 Activation at Cobalt: Catalytic Hydrogenation, Dehydrogenation, and Transfer Hydrogenation
We describe the synthesis of a cobalt (I)–N2 complex (2) supported by a meridional bis-
phosphino-boryl (PBP) ligand. Complex 2 undergoes a clean reaction with 2 equiv of …
phosphino-boryl (PBP) ligand. Complex 2 undergoes a clean reaction with 2 equiv of …
A mononuclear Fe (III) single molecule magnet with a 3/2↔ 5/2 spin crossover
The air stable complex [(PNP) FeCl2](1)(PNP= N [2-P (CHMe2) 2-4-methylphenyl] 2–),
prepared from one-electron oxidation of [(PNP) FeCl] with ClCPh3, displays an unexpected …
prepared from one-electron oxidation of [(PNP) FeCl] with ClCPh3, displays an unexpected …
Benchmark Study of Density Functional Theory Methods in Geometry Optimization of Transition Metal–Dinitrogen Complexes
The current benchmark study is focused on determining the most precise theoretical method
for optimizing the geometry of transition metal–dinitrogen complexes. To accomplish this …
for optimizing the geometry of transition metal–dinitrogen complexes. To accomplish this …
Effective Pincer Cobalt Precatalysts for Lewis Acid Assisted CO2 Hydrogenation
AZ Spentzos, CL Barnes, WH Bernskoetter - Inorganic Chemistry, 2016 - ACS Publications
The pincer ligand MeN [CH2CH2 (P i Pr2)] 2 (i PrPNP) was employed to support a series of
cobalt (I) complexes, which were crystallographically characterized. A cobalt monochloride …
cobalt (I) complexes, which were crystallographically characterized. A cobalt monochloride …
Bis (dinitrogen) cobalt (− 1) complexes with NHC ligation: synthesis, characterization, and their dinitrogen functionalization reactions affording side-on bound diazene …
Y Gao, G Li, L Deng - Journal of the American Chemical Society, 2018 - ACS Publications
Late-transition-metal-based catalysts are widely used in N2 fixation reactions, but the
reactivity of late-transition-metal N2 complexes, besides iron N2 complexes, has remained …
reactivity of late-transition-metal N2 complexes, besides iron N2 complexes, has remained …
Coordination chemistry insights into the role of alkali metal promoters in dinitrogen reduction
GP Connor, PL Holland - Catalysis today, 2017 - Elsevier
Abstract The Haber-Bosch process is a major contributor to fixed nitrogen that supports the
world's nutritional needs and is one of the largest-scale industrial processes known. It has …
world's nutritional needs and is one of the largest-scale industrial processes known. It has …
Metal–metal multiple bonding in C 3-symmetric bimetallic complexes of the first row transition metals
Metal–metal multiple bonds have been an intense area of focus in inorganic chemistry for
many decades as a result of their fundamentally interesting bonding properties, as well as …
many decades as a result of their fundamentally interesting bonding properties, as well as …
Nickel Complexes of a Pincer NN2 Ligand: Multiple Carbon−Chloride Activation of CH2Cl2 and CHCl3 Leads to Selective Carbon−Carbon Bond Formation
Z Csok, O Vechorkin, SB Harkins… - Journal of the …, 2008 - ACS Publications
A new pincer-type bis (amino) amine (NN2) ligand and its lithium and nickel complexes,
including Ni (II) methyl, ethyl, and phenyl complexes, were synthesized. The Ni (II) alkyl …
including Ni (II) methyl, ethyl, and phenyl complexes, were synthesized. The Ni (II) alkyl …