Automation and computer-assisted planning for chemical synthesis

Y Shen, JE Borowski, MA Hardy, R Sarpong… - Nature Reviews …, 2021 - nature.com
The molecules of today—the medicines that cure diseases, the agrochemicals that protect
our crops, the materials that make life convenient—are becoming increasingly sophisticated …

Catalytic Asymmetric Oxygenations with the Environmentally Benign Oxidants H2O2 and O2

KP Bryliakov - Chemical reviews, 2017 - ACS Publications
The discovery of simple and efficient catalyst systems for the asymmetric
oxofunctionalization of hydrocarbons is a challenging task of catalytic chemistry. In this …

Supramolecular catalysis. Part 1: non-covalent interactions as a tool for building and modifying homogeneous catalysts

M Raynal, P Ballester, A Vidal-Ferran… - Chemical Society …, 2014 - pubs.rsc.org
Supramolecular catalysis is a rapidly expanding discipline which has benefited from the
development of both homogeneous catalysis and supramolecular chemistry. The properties …

Asymmetric catalysis mediated by synthetic peptides, version 2.0: expansion of scope and mechanisms

AJ Metrano, AJ Chinn, CR Shugrue, EA Stone… - Chemical …, 2020 - ACS Publications
Low molecular weight synthetic peptides have been demonstrated to be effective catalysts
for an increasingly wide array of asymmetric transformations. In many cases, these peptide …

Ice flow of the Antarctic ice sheet

E Rignot, J Mouginot, B Scheuchl - Science, 2011 - science.org
We present a reference, comprehensive, high-resolution, digital mosaic of ice motion in
Antarctica assembled from multiple satellite interferometric synthetic-aperture radar data …

Chiral iron catalysts for asymmetric synthesis

K Gopalaiah - Chemical Reviews, 2013 - ACS Publications
Over the past few decades, asymmetric metal catalysis has become a major area in organic
chemistry. 1 This allows efficient access to a variety of important enantiomerically enriched …

Metal-catalyzed epoxidations of alkenes with hydrogen peroxide

BS Lane, K Burgess - Chemical reviews, 2003 - ACS Publications
Hydrogen peroxide is probably the best terminal oxidant after dioxygen with respect to
environmental and economic considerations. 1-4 Indeed, in certain circumstances, it is …

Advances in homogeneous and heterogeneous catalytic asymmetric epoxidation

QH **a, HQ Ge, CP Ye, ZM Liu, KX Su - Chemical Reviews, 2005 - ACS Publications
Barry Sharpless was awarded the 2001 Nobel Prize as a compliment to his great
contributions in the field of asymmetric epoxidation, which has been recognized as one of …

Green oxidation with aqueous hydrogen peroxide

R Noyori, M Aoki, K Sato - Chemical Communications, 2003 - pubs.rsc.org
Aqueous H2O2 is an ideal oxidant, when coupled with a tungstate complex and a
quaternary ammonium hydrogensulfate as an acidic phase-transfer catalyst. It oxidizes …

Biomimetic asymmetric catalysis

X **ao, K Xu, ZH Gao, ZH Zhu, C Ye, B Zhao… - Science China …, 2023 - Springer
Enzymes are the core for biological transformations in nature. Their structures and functions
have drawn enormous attention from biologists as well as chemists since last century. The …