Stereospecific olefin polymerization with chiral metallocene catalysts

HH Brintzinger, D Fischer, R Mülhaupt… - … Edition in English, 1995 - Wiley Online Library
Current studies on novel, metallocenebased catalysts for the polymerization of α‐olefins
have far‐reaching implications for the development of new materials as well as for the …

Selectivity in propene polymerization with metallocene catalysts

L Resconi, L Cavallo, A Fait, F Piemontesi - Chemical Reviews, 2000 - ACS Publications
The outstandingly rapid scientific and technological development of metallocene-based
catalysts for olefin polymerization is a perfect example of the successful application of …

Evidence for slow mixing across the pycnocline from an open-ocean tracer-release experiment

JR Ledwell, AJ Watson, CS Law - Nature, 1993 - nature.com
THE distributions of heat, salt and trace substances in the ocean thermocline depend on
mixing along and across surfaces of equal density (isopycnal and diapycnal mixing …

Cationic zirconocene olefin polymerization catalysts based on the organo-Lewis acid tris (pentafluorophenyl) borane. A synthetic, structural, solution dynamic, and …

X Yang, CL Stern, TJ Marks - Journal of the American Chemical …, 1994 - ACS Publications
The reaction of B (CeFs) 3 with zirconocene dimethyl complexes L2ZrMe2 in hydrocarbon
solvents affords base-free cationic zirconium complexes L2ZrMe+ MeB (C6F5) 3~(L= t/5 …

[BOOK][B] Activation and catalytic reactions of saturated hydrocarbons in the presence of metal complexes

AE Shilov, GB Shul'pin - 2001 - books.google.com
hemistry is the science about breaking and forming of bonds between atoms. One of the
most important processes for organic chemistry is breaking bonds C–H, as well as C–C in …

Lanthanocene catalysts in selective organic synthesis

GA Molander, JAC Romero - Chemical reviews, 2002 - ACS Publications
Synthetic organic chemists have scoured the depths and breadth of the periodic table in
search of novel, unique, and efficient methods to assemble small molecules. Metal …

Recent developments in organolanthanide polymerization catalysts

Z Hou, Y Wakatsuki - Coordination Chemistry Reviews, 2002 - Elsevier
This review describes recent advances in the synthesis and polymerization chemistry of
organolanthanide complexes (including those of scandium and yttrium), with emphasis …

Catalytic carbon-carbon bond cleavage and carbon-element bond formation give new life for polyolefins as biodegradable surfactants

U Kanbur, G Zang, AL Paterson, P Chatterjee… - Chem, 2021 - cell.com
Catalytic methods that introduce functional groups via carbon–carbon bond cleavage steps
have typically been limited to moieties activated by strain or by directing groups, with few …

Synthesis, structure, and reactions of hydride, borohydride, and aluminohydride compounds of the f-elements

M Ephritikhine - Chemical reviews, 1997 - ACS Publications
The huge interest of the hydride complexes of the d-transition metals is expressed by the
thousands of articles, reviews, and books devoted to their synthesis, structure, and reactivity …

Activation of a carbon–carbon bond in solution by transition-metal insertion

M Gozin, A Weisman, Y Ben-David, D Milstein - Nature, 1993 - nature.com
CLEAVAGE of carbon–carbon bonds by transition-metal-containing heterogeneous
catalysts forms the basis of one of the most important industrial processes, the refining of …