A survey of the state-of-the-art in the development of synthetic methods to incorporate p-
block elements into polymers is given. The incorporation of main group elements (groups 13 …

The field of amine borane chemistry has seen significant advances and fascinating
developments in the last decade, mostly driven by the potential use of hydrogen-rich amine …

The iron complex [FeH (CO)(PNP)](PNP= N (CH2CH2P i Pr2) 2) is a highly active catalyst
for ammonia borane dehydrocoupling at room temperature. Mainly linear polyaminoborane …

A detailed catalytic, stoichiometric, and mechanistic study on the dehydrocoupling of H3B·
NMe2H and dehydropolymerization of H3B· NMeH2 using the [Rh (Xantphos)]+ fragment is …

Ammonia–borane (AB) has been in the spotlight for its much touted potential as an onboard
vehicular hydrogen delivery material. Over the past decade, catalyzed dehydrogenation …

Mechanism is a core chemical concept that has vital implications for reaction rate, efficiency
and selectivity. The discovery of mechanism is not easy due to the great diversity of possible …

Amine–boranes have gained a lot of attention due to their potential as hydrogen storage
materials and their capacity to act as precursors for transfer hydrogenation. Therefore, a lot …

The pincer d8-monohydride complex RhH {xant (PiPr2) 2}(xant (PiPr2) 2= 9, 9-dimethyl-4, 5-
bis (diisopropylphosphino) xanthene) promotes the release of 1 equiv of hydrogen from …

High molar weight polyphosphinoboranes represent materials with auspicious properties,
but their preparation requires transition metal‐based catalysts. Here, calix [4] pyrrolato …

Complex OsH2 (CO)(PiPr3) 2, generated from OsH2 (CO)(η2-CH2 CHEt)(PiPr3) 2 by
dissociation of the olefin, promotes the release of 1 equiv of H2 from ammonia-borane and …