Synthetic photoelectrochemistry (PEC) is receiving increasing attention as a new frontier for
the generation and handling of reactive intermediates. PEC permits selective single …

Catalytic C–H bond activation, which was an elusive subject of chemical research until the
1990s, has now become a standard synthetic method for the formation of new C–C and C …

As two coexisting and fast-growing research fields in modern synthetic chemistry, the
merging of organocatalysis and C–H bond functionalization is well foreseeable, and the joint …

Azines, which are six-membered aromatic compounds containing one or more nitrogen
atoms, serve as ubiquitous structural cores of aromatic species with important applications in …

C− C bond formation is a fundamental transformation in organic synthesis. The development
of new synthetic methodology could be considered as a way of pursuing a novel method for …

Transition-metal-catalyzed reactions have been studied since the very beginning of the past
century and represent a great success in organic chemistry, along with the birth and growth …

Phenalenyl, a zigzag-edged odd alternant hydrocarbon unit can be found in the graphene
nanosheet. Hückel molecular orbital calculations indicate the presence of a nonbonding …

The electron is an efficient catalyst for conducting various types of radical cascade reaction
that proceed by way of radical and radical ion intermediates. But because electrons are …

The site-selective formation of carbonrcarbon bonds through direct functionalizations of
otherwise unreactive carbonrhydrogen bonds constitutes an economically attractive strategy …

We report a late‐stage heteroarylation of aryl sulfonium salts through activation with α‐
amino alkyl radicals in a mechanistically distinct approach from previously reported halogen …