The chemistry of heterocyclic carbenes has experienced a rapid development over the last
years. In addition to the imidazolin‐2‐ylidenes, a large number of cyclic diaminocarbenes …

A wide array of forms of palladium has been utilized as precatalysts for Heck and Suzuki
coupling reactions over the last 15 years. Historically, nearly every form of palladium used …

Bright and efficient chiral coinage metal clusters show promise for use in emerging circularly
polarized light-emitting materials and diodes. To date, highly efficient circularly polarized …

Abstract Palladium‐catalyzed C C and C N bond‐forming reactions are among the most
versatile and powerful synthetic methods. For the last 15 years, N‐heterocyclic carbenes …

During the last decade, the use of N-heterocyclic carbene ligands (NHCs) based on
imidazolium ions and related heterocycles has emerged as an alternative to phosphines in …

The continuous growth of N-heterocyclic carbene (NHC) chemistry is a fact that is pointed
out in all the introductions of the publications regarding NHCs that have appeared in the …

The use of N-heterocyclic carbenes as ligands for transition metals has increased
dramatically in the last few years, spurred on by their remarkable successes in the areas of …

Complexes of metals with N-heterocyclic carbene ligands (M/NHC) are typically considered
the systems of choice in homogeneous catalysis due to their stable metal–ligand framework …

The current status (up to 31 July 2006) of Ag (I)–NHCs (NHC= N-heterocyclic carbene) is
presented with various NHC systems ranging from five membered to seven membered rings …

Rhodium and iridium complexes of N-heterocyclic carbenes (3a− c and 4a− c) were
obtained by transmetalation from the corresponding Ag (I) complexes. The structure of 3b …