Aqueous alteration of silicate glass: state of knowledge and perspectives

S Gin, JM Delaye, F Angeli, S Schuller - npj Materials Degradation, 2021 - nature.com
The question of silicate glass chemical durability is at the heart of many industrial and
environmental issues, with certain glasses, such as bioglasses, needing to transform rapidly …

Recent advances in corrosion science applicable to disposal of high-level nuclear waste

GS Frankel, JD Vienna, J Lian, X Guo, S Gin… - Chemical …, 2021 - ACS Publications
High-level radioactive waste is accumulating at temporary storage locations around the
world and will eventually be placed in deep geological repositories. The waste forms and …

Matrices for radioactive waste immobilization: a review

RK Pilania, CL Dube - Frontiers in Materials, 2023 - frontiersin.org
Nuclear energy is considered a clean, reliable, and an inexhaustible energy source for
power generation. Nuclear power is harnessed from nuclear fission reactions in a dedicated …

Non-destructive 3D exploration of silicate glass corrosion: a combined multiscale approach from the macro to the nanoscale

G Franceschin, R Zanini, G Iori, E Longo… - Physical Chemistry …, 2024 - pubs.rsc.org
In this research, a comprehensive multi-technique analysis, including synchrotron-based X-
ray micro-computed tomography, is used to visualize the microstructure of alteration in a …

Deciphering the non-linear impact of Al on chemical durability of silicate glass

K Damodaran, JM Delaye, AG Kalinichev, S Gin - Acta Materialia, 2022 - Elsevier
The role of Al in aluminosilicate glasses remains somewhat a mystery: at low concentrations,
it increases the resistance to hydrolysis of the glass, whereas at high concentrations an …

On the effect of Al on alumino-borosilicate glass chemical durability

K Damodaran, S Gin, S Narayanasamy… - npj Materials …, 2023 - nature.com
The chemical durability of borosilicate glass used to confine nuclear wastes is known to vary
nonlinearly with their composition, making glass dissolution rate predictions difficult. Here …

Leaching and reactivity at the sodium aluminosilicate glass–water interface: insights from a ReaxFF molecular dynamics study

H Jabraoui, S Gin, T Charpentier, R Pollet… - The Journal of …, 2021 - ACS Publications
In this study, we used ReaxFF reactive force field molecular dynamics (MD) simulations to
investigate the dynamics associated with reactivity at the sodium aluminosilicate (NAS) …

Effect of structural disorder induced by external irradiation with heavy ions on the alteration of a four oxide borosilicate glass

S Gin, M Taron, H Arena, JM Delaye - npj Materials Degradation, 2024 - nature.com
The irradiation of glass by heavy ions induces structural damage, generally leading to a
decrease in its chemical durability whose amplitude strongly depends on the glass chemical …

Insights into the mechanism and kinetics of dissolution of aluminoborosilicate glasses in acidic media: Impact of high ionic field strength cations

Q Qin, N Stone-Weiss, T Zhao, P Mukherjee, J Ren… - Acta Materialia, 2023 - Elsevier
Achieving thinner and higher performance display/substrate glasses and transparent glass-
ceramics with tunable properties requires a precise control of acid-etching process, thus …

Review of corrosion interactions between different materials relevant to disposal of high-level nuclear waste

X Guo, S Gin, GS Frankel - npj Materials Degradation, 2020 - nature.com
This review covers the corrosion interactions between different materials that are relevant to
the disposal of high-level nuclear waste, in particular the waste forms and containers. The …