The role and fate of cap** ligands in colloidally prepared metal nanoparticle catalysts

LM Rossi, JL Fiorio, MAS Garcia, CP Ferraz - Dalton Transactions, 2018 - pubs.rsc.org
Metal nanoparticles have received intense scientific attention in the field of catalysis. Precise
engineering of nanomaterials' size, shape and surface composition, including adsorbed …

Controlling the surface environment of heterogeneous catalysts using self-assembled monolayers

CA Schoenbaum, DK Schwartz… - Accounts of Chemical …, 2014 - ACS Publications
Conspectus Rationally designing and producing suitable catalysts to promote specific
reaction pathways remains a major objective in heterogeneous catalysis. One approach …

Catalytic oxidation of methane: Pd and beyond

M Monai, T Montini, RJ Gorte… - European Journal of …, 2018 - Wiley Online Library
This brief review is focused on recent advancements in methane catalytic oxidation, an
important reaction for environmental remediation and clean power generation. Particular …

Ligand density quantification on colloidal inorganic nanoparticles

AM Smith, KA Johnston, SE Crawford, LE Marbella… - Analyst, 2017 - pubs.rsc.org
Colloidal inorganic nanoparticles are being used in an increasingly large number of
applications ranging from biological imaging to television displays. In all cases, nanoparticle …

Visualizing formation of high entropy alloy nanoparticles with liquid phase transmission electron microscopy

J Sun, A Leff, Y Li, TJ Woehl - Nanoscale, 2023 - pubs.rsc.org
High entropy alloy (HEA) nanoparticles hold promise as active and durable (electro)
catalysts. Understanding their formation mechanism will enable rational control over …

Universal click-chemistry approach for the DNA functionalization of nanoparticles

N Siegel, H Hasebe, G Chiarelli, D Garoli… - Journal of the …, 2024 - ACS Publications
Nanotechnology has revolutionized the fabrication of hybrid species with tailored
functionalities. A milestone in this field is the deoxyribonucleic acid (DNA) conjugation of …

Effects of thiol modifiers on the kinetics of furfural hydrogenation over Pd catalysts

SH Pang, CA Schoenbaum, DK Schwartz… - Acs Catalysis, 2014 - ACS Publications
Thiolate self-assembled monolayers (SAMs) were used to block specific active sites on
Pd/Al2O3 during the hydrogenation of furfural to elucidate site requirements for each …