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Artificial molecular ratchets: tools enabling endergonic processes
Non‐equilibrium chemical systems underpin multiple domains of contemporary interest,
including supramolecular chemistry, molecular machines, systems chemistry, prebiotic …
including supramolecular chemistry, molecular machines, systems chemistry, prebiotic …
Energy and information flows in autonomous systems
Multi-component molecular machines are ubiquitous in biology. We review recent progress
on describing their thermodynamic properties using autonomous bipartite Markovian …
on describing their thermodynamic properties using autonomous bipartite Markovian …
Variance sum rule for entropy production
Entropy production is the hallmark of nonequilibrium physics, quantifying irreversibility,
dissipation, and the efficiency of energy transduction processes. Despite many efforts, its …
dissipation, and the efficiency of energy transduction processes. Despite many efforts, its …
Circuit theory for chemical reaction networks
We lay the foundation of a circuit theory for chemical reaction networks. Chemical reactions
are grouped into chemical modules solely characterized by their current-concentration …
are grouped into chemical modules solely characterized by their current-concentration …
Effective estimation of entropy production with lacking data
Observing stochastic trajectories with rare transitions between states, practically
undetectable on time scales accessible to experiments, makes it impossible to directly …
undetectable on time scales accessible to experiments, makes it impossible to directly …
Calcium oscillations optimize the energetic efficiency of mitochondrial metabolism
Energy transduction is central to living organisms, but the impact of enzyme regulation and
signaling on its thermodynamic efficiency is generally overlooked. Here, we analyze the …
signaling on its thermodynamic efficiency is generally overlooked. Here, we analyze the …
A Nernst heat theorem for nonequilibrium jump processes
We discuss via general arguments and examples when and why the steady nonequilibrium
heat capacity vanishes with temperature. The framework is that of Markov jump processes …
heat capacity vanishes with temperature. The framework is that of Markov jump processes …
Molecular-scale dissipative chemistry drives the formation of nanoscale assemblies and their macroscale transport
Fuelled chemical systems have considerable functional potential that remains largely
unexplored. Here we report an approach to transient amide bond formation and use it to …
unexplored. Here we report an approach to transient amide bond formation and use it to …
Methods and conversations in (post) modern thermodynamics
Lecture notes after the doctoral school (Post) Modern Thermodynamics held at the
University of Luxembourg, December 2022, 5-7, covering and advancing continuous-time …
University of Luxembourg, December 2022, 5-7, covering and advancing continuous-time …
Elementary Flux Modes as CRN Gears for Free Energy Transduction
M Bilancioni, M Esposito - arxiv preprint arxiv:2405.17960, 2024 - arxiv.org
We demonstrate that, for a chemical reaction network (CRN) engaged in energy
transduction, its optimal operation from a thermodynamic efficiency standpoint is contingent …
transduction, its optimal operation from a thermodynamic efficiency standpoint is contingent …