The synthesis of new types of mono-and polynuclear ruthenium nitrosyl complexes is driving
progress in the field of NO generation for a variety of applications. Light-induced Ru-NO …

Formulating insightful questions and experiments is crucial to the advancement of science.
The purpose of this Perspective is to encourage scientists in all areas of chemistry to ask …

Over the last 15 years or so, it has been shown that low‐valent, electron‐rich uranium (III)
complexes exhibit a wide variety of reactivity towards small molecules. As a result, the field …

The potential of redox-active ligands to behave “noninnocently” in transition-metal
coordination compounds is reflected with respect to various aspects and situations. These …

Direct conversion of dinitrogen (N2) into organic compounds, not through ammonia (NH3), is
of great significance both fundamentally and practically. Here we report a highly efficient …

The La2+ complex [K (18-crown-6)(OEt2)][Cp ″3La](1)[Cp ″= C5H3 (SiMe3) 2-1, 3], can
be synthesized under N2, but in the presence of KC5Me5, 1 reduces N2 to the (N N) 2 …

Molecular complexes of uranium are capable of activating a range of industrially and
economically important small molecules such as CO, CO2, and N2; new and often …

Herein we present a series of new α-iminopyridine-based iron-PNN pincer complexes
[FeBr2LPNN](1),[Fe (CO) 2LPNN](2),[Fe (CO) 2LPNN](BF4)(3),[Fe (F)(CO) 2LPNN](BF4)(4) …

Iron–nitrosyls have fascinated chemists for a long time due to the noninnocent nature of the
NO ligand that can exist in up to five different oxidation and spin states. Coordination to an …

The dinitrogen (N2) chemistry of lanthanides remains less developed compared to the d‐
block metals and lanthanide‐promoted N2 functionalization chemistry in well‐defined …