Best‐practice DFT protocols for basic molecular computational chemistry

M Bursch, JM Mewes, A Hansen… - Angewandte Chemie …, 2022 - Wiley Online Library
Nowadays, many chemical investigations are supported by routine calculations of molecular
structures, reaction energies, barrier heights, and spectroscopic properties. The lion's share …

Delocalization error: The greatest outstanding challenge in density‐functional theory

KR Bryenton, AA Adeleke, SG Dale… - Wiley Interdisciplinary …, 2023 - Wiley Online Library
Every day, density‐functional theory (DFT) is routinely applied to computational modeling of
molecules and materials with the expectation of high accuracy. However, in certain …

Dispersion-corrected mean-field electronic structure methods

S Grimme, A Hansen, JG Brandenburg… - Chemical …, 2016 - ACS Publications
Mean-field electronic structure methods like Hartree–Fock, semilocal density functional
approximations, or semiempirical molecular orbital (MO) theories do not account for long …

Toward the next generation of density functionals: Esca** the zero-sum game by using the exact-exchange energy density

M Kaupp, A Wodyński, AV Arbuznikov… - Accounts of Chemical …, 2024 - ACS Publications
Conspectus Kohn–Sham density functional theory (KS DFT) is arguably the most widely
applied electronic-structure method with tens of thousands of publications each year in a …

Full implementation, optimization, and evaluation of a range-separated local hybrid functional with wide accuracy for ground and excited states

S Fürst, M Haasler, R Grotjahn… - Journal of Chemical …, 2023 - ACS Publications
We report the first full and efficient implementation of range-separated local hybrid
functionals (RSLHs) into the TURBOMOLE program package. This enables the computation …

Embedding methods for quantum chemistry: applications from materials to life sciences

LO Jones, MA Mosquera, GC Schatz… - Journal of the American …, 2020 - ACS Publications
Quantum mechanical embedding methods hold the promise to transform not just the way
calculations are performed, but to significantly reduce computational costs and improve …

Local hybrid functionals: Theory, implementation, and performance of an emerging new tool in quantum chemistry and beyond

TM Maier, AV Arbuznikov… - Wiley Interdisciplinary …, 2019 - Wiley Online Library
The state of the art in the development, implementation, validation, and application of local
hybrid functionals with position‐dependent exact‐exchange admixture is reviewed …

Assessing the accuracy of local hybrid density functional approximations for molecular response properties

C Holzer, YJ Franzke, M Kehry - Journal of Chemical Theory and …, 2021 - ACS Publications
A comprehensive overview of the performance of local hybrid functionals for molecular
properties like excited states, ionization potentials within the GW framework, polarizabilities …

Long-range corrected hybrid functionals for π-conjugated systems: Dependence of the range-separation parameter on conjugation length

T Körzdörfer, JS Sears, C Sutton… - The Journal of chemical …, 2011 - pubs.aip.org
Long-range corrected (range-separated hybrid) functionals represent a relatively new class
of functionals for generalized Kohn-Sham theory that have proven to be very successful, for …

New concepts and modeling strategies to design and evaluate photo-electro-catalysts based on transition metal oxides

P Liao, EA Carter - Chemical Society Reviews, 2013 - pubs.rsc.org
Photocatalytic production of transportation fuels should be among our long term strategies to
achieve energy and environmental sustainability for the planet, but the technology is …