Operando modeling of zeolite-catalyzed reactions using first-principles molecular dynamics simulations

V Van Speybroeck, M Bocus, P Cnudde… - ACS …, 2023 - ACS Publications
Within this Perspective, we critically reflect on the role of first-principles molecular dynamics
(MD) simulations in unraveling the catalytic function within zeolites under operating …

Sensing and sensitivity: Computational chemistry of graphene‐based sensors

A Piras, C Ehlert, G Gryn'ova - Wiley Interdisciplinary Reviews …, 2021 - Wiley Online Library
Highly efficient, tunable, biocompatible, and environmentally friendly electrochemical
sensors featuring graphene‐based materials pose a formidable challenge for computational …

[HTML][HTML] Sparse tensor based nuclear gradients for periodic Hartree–Fock and low-scaling correlated wave function methods in the CP2K software package: A …

A Bussy, O Schütt, J Hutter - The Journal of Chemical Physics, 2023 - pubs.aip.org
The development of novel double-hybrid density functionals offers new levels of accuracy
and is leading to fresh insights into the fundamental properties of matter. Hartree–Fock exact …

Doubly hybrid functionals close to chemical accuracy for both finite and extended systems: implementation and test of XYG3 and XYGJ-OS

Y Wang, Y Li, J Chen, IY Zhang, X Xu - JACS Au, 2021 - ACS Publications
While being widely used to understand the chemical reactions in heterogeneous catalysis or
other multidisciplinary systems, a great challenge that semilocal and hybrid density …

Integral-Direct Hartree–Fock and Møller–Plesset Perturbation Theory for Periodic Systems with Density Fitting: Application to the Benzene Crystal

SJ Bintrim, TC Berkelbach, HZ Ye - Journal of Chemical Theory …, 2022 - ACS Publications
We present an algorithm and implementation of integral-direct, density-fitted Hartree–Fock
(HF) and second-order Møller–Plesset perturbation theory (MP2) for periodic systems. The …

Connectivity defects in metallo-supramolecular polymer networks at different self-sorting regimes

M Ahmadi, L Löser, G Pareras, A Poater… - Chemistry of …, 2023 - ACS Publications
The properties of polymer networks depend on their connectivity, specifically on the
presence of connectivity defects like loops and dangling ends. While chemically crosslinked …

[HTML][HTML] Massively parallel implementation of gradients within the random phase approximation: Application to the polymorphs of benzene

F Stein, J Hutter - The Journal of Chemical Physics, 2024 - pubs.aip.org
The Random-Phase approximation (RPA) provides an appealing framework for semi-local
density functional theory. In its Resolution-of-the-Identity (RI) approach, it is a very accurate …

Insight into the Fergusonite–Scheelite phase transition of ABO4-type oxides by density functional theory: a case study of the subtleties of the ground state of BiVO4

T Liu, X Zhang, J Guan, CRA Catlow… - Chemistry of …, 2022 - ACS Publications
BiVO4 (BVO) is an important photocatalytic and ferroelastic material. It has been extensively
studied using density functional theory (DFT). However, on optimization, at a commonly …

Benchmarking the computational costs and quality of vibrational spectra from ab initio simulations

S Taherivardanjani, R Elfgen… - Advanced Theory …, 2022 - Wiley Online Library
The scaling behavior of ab initio molecular dynamics simulations for the different size bulk
systems of liquid methanol is presented and thereby the characteristics of every system …

Can spin-component scaled MP2 achieve kJ/mol accuracy for cohesive energies of molecular crystals?

YH Liang, HZ Ye, TC Berkelbach - The Journal of Physical …, 2023 - ACS Publications
Attaining kJ/mol accuracy in cohesive energy for molecular crystals is a persistent challenge
in computational materials science. In this study, we evaluate second-order Møller–Plesset …