Cyanide-bridged assemblies with tricyanometalates

T Shiga, N Mihara, M Nihei - Coordination Chemistry Reviews, 2022 - Elsevier
Prussian blue, Fe III 4 [Fe II (CN) 6] 3· nH 2 O (n= 14∼ 16), is one of the most classical mixed-
valence complexes and was used as pigments. Combinations of different metal ions lead to …

Recent advances in metal cluster-containing spin-crossover coordination compounds

G Yang, ZP Ni, ML Tong - Coordination Chemistry Reviews, 2024 - Elsevier
Spin crossover (SCO) complexes are classic magnetic bistable materials with various
promising potential applications, such as data storage, displays, switches, actuators and …

Oriented proton-conductive nano-sponge-facilitated polymer electrolyte membranes

X Liu, J Zhang, C Zheng, J Xue, T Huang… - Energy & …, 2020 - pubs.rsc.org
Achieving high power output from proton exchange membrane fuel cells (PEMFCs) requires
efficient proton transport in proton exchange membranes (PEMs). Since proton conductivity …

Cyanide single-molecule magnets exhibiting solvent dependent reversible “on” and “off” exchange bias behavior

D Pinkowicz, HI Southerland, C Avendaño… - Journal of the …, 2015 - ACS Publications
The syntheses, structures, and magnetic properties of four new complex salts,(PPN){[MnIII
(salphen)(MeOH)] 2 [MIII (CN) 6]}· 7MeOH (Mn2M· 7MeOH)(M= Fe, Ru, Os and Co; PPN+ …

High-performance luminescence thermometer with field-induced slow magnetic relaxation based on a heterometallic cyanido-bridged 3d–4f complex

V Tangoulis, V Nastopoulos, N Panagiotou… - Inorganic …, 2022 - ACS Publications
The 1: 1: 1 reaction of DyCl3· 6H2O, K3 [Co (CN) 6] and bpyO2 in H2O has provided access
to a complex with formula [DyCo (CN) 6 (bpyO2) 2 (H2O) 3]· 4H2O (1) in a very good yield …

Modular approach towards functional multimetallic coordination clusters

J Kobylarczyk, E Kuzniak, M Liberka, S Chorazy… - Coordination Chemistry …, 2020 - Elsevier
Polynuclear coordination clusters (PCCs) provide considerable design capabilities towards
various functions based on structural non-rigidity and spin state transitions, optical …

Tuning of Charge Transfer Assisted Phase Transition and Slow Magnetic Relaxation Functionalities in {Fe9–xCox[W(CN)8]6} (x = 0–9) Molecular Solid Solution

S Chorazy, JJ Stanek, W Nogas… - Journal of the …, 2016 - ACS Publications
Precisely controlled stoichiometric mixtures of Co2+ and Fe2+ metal ions were combined
with the [WV (CN) 8] 3–metalloligand in a methanolic solution to produce a series of …

TbCo and Tb 0.5 Dy 0.5 Co layered cyanido-bridged frameworks for construction of colorimetric and ratiometric luminescent thermometers

K Kumar, S Chorazy, K Nakabayashi, H Sato… - Journal of Materials …, 2018 - pubs.rsc.org
Heterometallic cyanido-bridged networks are versatile molecular platforms for diverse
optical, magnetic and electronic functionalities. We present a pioneering synthetic route …

Smart ligands for efficient 3d-, 4d-and 5d-metal single-molecule magnets and single-ion magnets

PS Perlepe, D Maniaki, E Pilichos, E Katsoulakou… - Inorganics, 2020 - mdpi.com
There has been a renaissance in the interdisciplinary field of Molecular Magnetism since~
2000, due to the discovery of the impressive properties and potential applications of d-and f …

FeII Spin‐Crossover Phenomenon in the Pentadecanuclear {Fe9[Re(CN)8]6} Spherical Cluster

S Chorazy, R Podgajny, K Nakabayashi… - Angewandte Chemie …, 2015 - Wiley Online Library
The self‐assembly of iron (II) ions with rare octacyanidorhenate (V) metalloligands in a
methanolic solution results in the formation of a nanometric pentadecanuclear {FeII9 [ReV …