Designing sites in heterogeneous catalysis: are we reaching selectivities competitive with those of homogeneous catalysts?
F Zaera - Chemical Reviews, 2022 - ACS Publications
A critical review of different prominent nanotechnologies adapted to catalysis is provided,
with focus on how they contribute to the improvement of selectivity in heterogeneous …
with focus on how they contribute to the improvement of selectivity in heterogeneous …
Surface organometallic chemistry in heterogeneous catalysis
The broad challenges of energy and environment have become a main focus of research
efforts to develop more active and selective catalytic systems for key chemical …
efforts to develop more active and selective catalytic systems for key chemical …
Single‐atom catalysts supported on ordered porous materials: Synthetic strategies and applications
Single‐atom catalysts (SACs) are attracting extensive attention due to their incredibly
catalytic activity and selectivity, high utilization of metal atoms, and obvious cost reduction …
catalytic activity and selectivity, high utilization of metal atoms, and obvious cost reduction …
Consequences of confinement for alkene epoxidation with hydrogen peroxide on highly dispersed group 4 and 5 metal oxide catalysts
Ti, Nb, and Ta atoms substituted into the framework of zeolite* BEA (M-BEA) or grafted onto
mesoporous silica (M-SiO2) irreversibly activate hydrogen peroxide (H2O2) to form pools of …
mesoporous silica (M-SiO2) irreversibly activate hydrogen peroxide (H2O2) to form pools of …
Periodic trends in olefin epoxidation over group IV and V framework-substituted zeolite catalysts: a kinetic and spectroscopic study
Group IV and V framework-substituted zeolites have been used for olefin epoxidation
reactions for decades, yet the underlying properties that determine the selectivities and …
reactions for decades, yet the underlying properties that determine the selectivities and …
Alkene Epoxidations with H2O2 over Groups 4–6 Metal-Substituted BEA Zeolites: Reactive Intermediates, Reaction Pathways, and Linear Free-Energy …
Rates and selectivities for alkene epoxidations depend sensitively on the identity of the
active metal center for both heterogeneous and homogeneous catalysts. While group 6 …
active metal center for both heterogeneous and homogeneous catalysts. While group 6 …
Toward a Better Understanding of Intrinsic Activity Trends in Zr-Based Heterogeneous Catalysts for Meerwein–Pondorf–Verley Reduction of Levulinate Esters
Lewis acidic heterogeneous catalysts are known to be active for transfer hydrogenation of
carbonyl compounds, which occur naturally or can be derived from renewable feedstocks …
carbonyl compounds, which occur naturally or can be derived from renewable feedstocks …
A review of the role of hydrogen peroxide in organic transformations
H Targhan, P Evans, K Bahrami - Journal of Industrial and Engineering …, 2021 - Elsevier
Under appropriate conditions, hydrogen peroxide is able to perform a multitude of oxidative
organic reactions in an economically, technically, and environmentally satisfying manner …
organic reactions in an economically, technically, and environmentally satisfying manner …
Metal organic frameworks as heterogeneous catalysts in olefin epoxidation and carbon dioxide cycloaddition
A Tombesi, C Pettinari - Inorganics, 2021 - mdpi.com
Metal–organic frameworks (MOFs) are a family of porous crystalline materials that serve in
some cases as versatile platforms for catalysis. In this review, we overview the recent …
some cases as versatile platforms for catalysis. In this review, we overview the recent …
Insight into pathways of methylene blue degradation with H2O2 over mono and bimetallic Nb, Zn oxides
L Wolski, M Ziolek - Applied Catalysis B: Environmental, 2018 - Elsevier
The aim of this work was to investigate the influence of surface properties of metal oxides
(Nb 2 O 5, ZnO and ZnNb 2 O 6) on the type of reactive oxygen species (ROS) formed in …
(Nb 2 O 5, ZnO and ZnNb 2 O 6) on the type of reactive oxygen species (ROS) formed in …