Spatially-controlled complex molecules and their applications
The understanding of molecular structure and function is at the very heart of the chemical
and molecular sciences. Experiments that allow for the creation of structurally pure samples …
and molecular sciences. Experiments that allow for the creation of structurally pure samples …
Conformer-specific photochemistry imaged in real space and time
Conformational isomers (conformers) of molecules play a decisive role in biology and
organic chemistry. However, experimental methods for investigating chemical reaction …
organic chemistry. However, experimental methods for investigating chemical reaction …
Specific Chemical Reactivities of Spatially Separated 3-Aminophenol Conformers with Cold Ca+ Ions
YP Chang, K Długołęcki, J Küpper, D Rösch, D Wild… - Science, 2013 - science.org
Many molecules exhibit multiple rotational isomers (conformers) that interconvert thermally
and are difficult to isolate. Consequently, a precise characterization of their role in chemical …
and are difficult to isolate. Consequently, a precise characterization of their role in chemical …
Why does dimethyl carbonate dissociate Li salt better than other linear carbonates? Critical role of polar conformers
The marked difference in the ionic conductivities of linear carbonate (LC) electrolyte
solutions despite their similar viscosities and permittivities is a long-standing puzzle. This …
solutions despite their similar viscosities and permittivities is a long-standing puzzle. This …
Role of Solvent Isomerism in Mixed Carbonate Electrolytes for Li-Ion Batteries
Current Li-ion battery (LIB) electrolytes employ mixed solvents consisting of ethylene
carbonate (EC) and linear carbonates (LCs). Notably, the ion conductivities of the EC/LC …
carbonate (EC) and linear carbonates (LCs). Notably, the ion conductivities of the EC/LC …
From roaming atoms to hop** surfaces: map** out global reaction routes in photochemistry
S Maeda, T Taketsugu, K Ohno… - Journal of the american …, 2015 - ACS Publications
The photodissociation of small molecules occurs upon irradiation by ultraviolet or visible
light, and it is a very important chemical process in Earth's atmosphere, in the atmospheres …
light, and it is a very important chemical process in Earth's atmosphere, in the atmospheres …
Differentiating and quantifying gas-phase conformational isomers using Coulomb explosion imaging
Conformational isomerism plays a crucial role in defining the physical and chemical
properties and biological activity of molecules ranging from simple organic compounds to …
properties and biological activity of molecules ranging from simple organic compounds to …
Chemistry with controlled ions
S Willitsch - Advances in Chemical Physics, 2017 - Wiley Online Library
This chapter focuses on the application of controlled‐molecule techniques for precise
studies of ion‐molecule reactions in the gas phase. It gives an overview of the most …
studies of ion‐molecule reactions in the gas phase. It gives an overview of the most …
Switching on H-tunneling through conformational control
H-tunneling is a ubiquitous phenomenon, relevant to fields from biochemistry to materials
science, but harnessing it for mastering the manipulation of chemical structures still remains …
science, but harnessing it for mastering the manipulation of chemical structures still remains …
Conformationally controlled chemistry: Excited-state dynamics dictate ground-state reaction
Ion imaging reveals distinct photodissociation dynamics for propanal cations initially
prepared in either the cis or gauche conformation, even though these isomers differ only …
prepared in either the cis or gauche conformation, even though these isomers differ only …