Di-and tetranuclear dysprosium single-molecule magnets bridged by unprecedentedly disassembled nitrogen-enriched tetrazine derivatives

JT Chen, H Yan, TT Wang, TD Zhou… - Inorganic Chemistry, 2022 - ACS Publications
A series of di-and tetranuclear lanthanide complexes with the formulas [Dy2bmzch (tmhd) 5
(CH3OH)]· CH3OH (1),[Dy2bmzch (dbm) 4 (CH3O)(CH3OH)]· 0.5 CH3OH· 0.5 H2O (2), and …

Multifunctional Two-Dimensional Tetrazine-Based Polymer for an Inverse Electron Demand Diels–Alder Reaction and Room-Temperature NO2 Sensing

G Gorthala, AR K, RR Malakalapalli… - ACS Applied Polymer …, 2025 - ACS Publications
A multifunctional tetrazine-integrated π-conjugated two-dimensional (2D) porous organic
polymer (CMP)(PTz) has been developed by the self-condensation of benzene-1, 3, 5 …

Modulating quantum tunnelling of magnetization in Dy isotopologue dimers

TT Ruan, E Moreno-Pineda, S Paul, M Schulze… - Dalton …, 2024 - pubs.rsc.org
Qudits are anticipated to streamline quantum computation by minimizing iterations, lowering
error rates, and facilitating error correction. It has been shown that Dy (III)-based molecular …

The role of the radical tetrazine bridging ligand in spin-only magnetic coupling in complex dimers

K Al-Ameed, G Abass - New Journal of Chemistry, 2025 - pubs.rsc.org
This study explores unusual magnetic coupling between two metal centers in dimers
bridged by a tetrazine ring. Computational analysis was performed to understand how a …

Asymmetric Ring Opening in a Tetrazine‐Based Ligand Affords a Tetranuclear Opto‐Magnetic Ytterbium Complex

P Richardson, R Marin, Y Zhang… - … A European Journal, 2021 - Wiley Online Library
We report the formation of a tetranuclear lanthanide cluster,[Yb4 (bpzch) 2 (fod) 10](1),
which occurs from a serendipitous ring opening of the functionalised tetrazine bridging …

Synthesis of tetrazine-tetracyanobutadienes and their transformation into pyridazines via inverse-electron demand Diels–Alder cycloaddition (IEDDA)

AV Kamble, RR Malakalapalli - Organic & Biomolecular Chemistry, 2023 - pubs.rsc.org
We report the synthesis of novel triphenylamine–tetrazine–tetracyanobutadiene based
asymmetric and symmetric push–pull chromophores (1T and 1DT) by [2+ 2] cycloaddition …

[HTML][HTML] Synthesis and crystal structure of 2, 2, 2-trichloroethyl N-{4-[6-(1-hydroxyethyl)-1, 2, 4, 5-tetrazin-3-yl] benzyl} carbamate

J Voss, HG Stammler, N Sewald - Structure Reports, 2025 - journals.iucr.org
An orthogonally addressable 3, 6-disubstituted 1, 2, 4, 5-tetrazine, namely 2, 2, 2-
trichloroethyl N-{4-[6-(1-hydroxyethyl)-1, 2, 4, 5-tetrazin-3-yl] benzyl} carbamate …

Magnetic exchange coupling in 3d and 4f complexes using radical tetrazine-based frameworks

M Alves Lemes - 2019 - ruor.uottawa.ca
High symmetry and low coordinated single-ion lanthanides have been a successful recipe to
design high performance single molecule magnets (SMMs). However, enhancement of the …