Allenes in catalytic asymmetric synthesis and natural product syntheses

S Yu, S Ma - Angewandte Chemie International Edition, 2012 - Wiley Online Library
Allenes are the simplest class of cumulenes, with two contiguous C C bonds, and show
unique physical and chemical properties. These features make allenes particularly attractive …

[PDF][PDF] Catalytic Nazarov cyclization: the state of the art

T Vaidya, R Eisenberg, AJ Frontier - ChemInform, 2012 - academia.edu
The Nazarov reaction [1] permits stereospecific construction of a new carbon-carbon bond in
the pentadienyl cation (2) of divinyl ketones (1) through a 4π electrocyclic process (Scheme …

Allene in katalytischer asymmetrischer Synthese und Naturstoffsynthese

S Yu, S Ma - Angewandte Chemie, 2012 - Wiley Online Library
Allene–Verbindungen mit zwei benachbarten C C‐Bindungen–bilden die einfachste
Klasse unter den Cumulenen. Sie verfügen über außergewöhnliche physikalische und …

Nazarov reaction: current trends and recent advances in the synthesis of natural compounds and their analogs

MG Vinogradov, OV Turova, SG Zlotin - Organic & biomolecular …, 2017 - pubs.rsc.org
The Nazarov reaction (cyclization) is one of the most useful synthetic tools for the
stereoselective preparation of various cyclopentenone scaffolds. This review summarizes …

Silver and platinum-catalysed addition of O–H and N–H bonds to allenes

MP Muñoz - Chemical Society Reviews, 2014 - pubs.rsc.org
Transition-metal catalysed nucleophile addition to allenes is a very powerful tool for the
synthesis of functionalised molecules containing heteroatoms, heterocycles in the …

Complementary C–H Functionalization Mode of Benzoylacetonitriles: Computer-Augmented Study of a Regio-and Stereoselective Synthesis of Functionalized …

X Song, BN Do Doan, X Zhang, R Lee, X Fan - Organic letters, 2019 - ACS Publications
A highly regio-and stereoselective synthesis of functionalized benzofulvenes via Rh (III)-
catalyzed cascade reactions of benzoyl acetonitrile/methylsulfone/acetate with propargyl …

Natural deep eutectic solvents as an efficient and reusable active system for the Nazarov cyclization

S Nejrotti, M Iannicelli, SS Jamil, D Arnodo… - Green …, 2020 - pubs.rsc.org
Natural deep eutectic solvents have emerged as alternative non-toxic, non-aqueous
solvents for an increasing number of synthetic transformations. Remarkably, in some cases …

[PDF][PDF] Asymmetric Nazarov reaction catalyzed by chiral tris (oxazoline)/copper (II)

P Cao, C Deng, YY Zhou, XL Sun… - Angewandte Chemie …, 2010 - tangyong.sioc.ac.cn
The frequent occurrence of five-membered carbocycles in natural products and other
biologically active compounds has provided a major impetus for the development of efficient …

Coordination-induced stereocontrol over carbocations: asymmetric reductive deoxygenation of racemic tertiary alcohols

M Isomura, DA Petrone… - Journal of the American …, 2019 - ACS Publications
The inherent difficulty in eliciting facial control over carbocations has limited their utility as
intermediates in asymmetric catalysis. We have now shown that a docking strategy involving …

[BUCH][B] Silver Catalysis in Organic Synthesis, 2 Volume Set

CJ Li, X Bi - 2019 - books.google.com
Covers all the aspects of the recent achievements in silver catalyzed reactions Silver
catalysis has emerged as a powerful tool in the field of organic synthesis. This …