Covalent grafting of polyoxometalate hybrids onto flat silicon/silicon oxide: Insights from POMs layers on oxides

M Laurans, K Trinh, K Dalla Francesca… - … Applied Materials & …, 2020 - ACS Publications
Immobilization of polyoxometalates (POMs) onto oxides is relevant to many applications in
the fields of catalysis, energy conversion/storage, or molecular electronics. Optimization and …

Pyridine-based complexes of copper (II) chloride and bromide: ligand conformation effects on crystal structure. Synthesis, structure and magnetic behavior of Cu (2-Cl …

RJ Dubois, CP Landee, M Rademeyer… - Journal of …, 2019 - Taylor & Francis
Reaction of copper (II) chloride or bromide with 2-chloro-3-bromopyridine or 2, 3-
dichloropyridine generates a family of compounds of the general formula L 2 CuX 2 (1–4). X …

Heteroleptic iron (II) spin-crossover complexes based on a 2, 6-bis (pyrazol-1-yl) pyridine-type ligand functionalized with a carboxylic acid

V Garcia-Lopez, M Palacios-Corella… - Inorganic …, 2019 - ACS Publications
Two new heteroleptic complexes [Fe (1bppCOOH)(3bpp-bph)](ClO4) 2· solv (1· solv, solv=
various solvents; 1bppCOOH= 2, 6-bis (1 H-pyrazol-1-yl) isonicotinic acid; 3bpp-bph= 2, 6 …

A valence tautomeric cobalt–dioxolene complex with an anchoring group for prospective chemical grafting to metal oxides

M Mörtel, M Seller, FW Heinemann… - Dalton …, 2020 - pubs.rsc.org
Here, we synthesized a valence tautomeric cobalt–dioxolene complex featuring a protected
anchoring group. At room temperature, the complex reveals a nearly pure low-spin-Co (III) …

Crystal structure and catalytic properties of a vanadium complex cis-[VO2(Him-py)(im-py)]2·3H2O

M Sun, S Zhang, J Zhang, W **a, J Chen… - Journal of Coordination …, 2019 - Taylor & Francis
The coordination behavior of Him-py (2-(1H-imidazol-2-yl) pyridine) toward vanadium has
been explored. The six-coordinate complex, cis-[VO2 (Him-py)(im-py)] 2· 3H2O (1), was …

Crystal structure, NMR and catalytic properties of a bis-peroxovanadium [NH4][VO(O2)2(mpa)]·H2O

P Chen, S Zhang, J Zhang, W **a… - Journal of Coordination …, 2019 - Taylor & Francis
By reacting NH4VO3 and mpa (mpa= 4-methoxypicolinamide) in the presence of H2O2, a
bis-peroxovanadium [NH4][VO (O2) 2 (mpa)]· H2O (1) was obtained and characterized by X …