Rational Design of Electrocatalysts for Water Oxidation Reaction: Inspiration from Photosystem II

H Li, F Lang, M Liu, X Zhang, D Yang, J Zhang… - …, 2023 - Wiley Online Library
To address the ever‐increasing societal demand for clean energy, electrocatalytic water
splitting has attracted considerable interest for the efficient production of H2 and O2 …

Identification, Characterization, and Electronic Structures of Interconvertible Cobalt–Oxygen TAML Intermediates

DD Malik, W Ryu, Y Kim, G Singh, JH Kim… - Journal of the …, 2024 - ACS Publications
The reaction of Li [(TAML) CoIII]· 3H2O (TAML= tetraamido macrocyclic tetraanionic ligand)
with iodosylbenzene at 253 K in acetone in the presence of redox-innocent metal ions (Sc …

An intramolecular cobalt-peptoid complex as an efficient electrocatalyst for water oxidation at low overpotential

S Pahar, G Maayan - Chemical Science, 2024 - pubs.rsc.org
Water electrolysis is the simplest way to produce hydrogen, as a clean renewable fuel.
However, the high overpotential and slow kinetics hamper its applicability. Designing …

A Water‐Soluble Highly Oxidizing Cobalt Molecular Catalyst Designed for Bioinspired Water Oxidation

YF Su, WZ Luo, WQ Lin, YB Su, ZJ Li… - Angewandte …, 2022 - Wiley Online Library
Herein, we present a stable water‐soluble cobalt complex supported by a dianionic 2, 2′‐
([2, 2′‐bipyridine]‐6, 6′‐diyl) bis (propan‐2‐ol) ligand scaffold, which is a rare example of …

Characterization of Reaction Intermediates Involved in the Water Oxidation Reaction of a Molecular Cobalt Complex

M Bera, S Kaur, K Keshari, D Moonshiram… - Inorganic …, 2022 - ACS Publications
Molecular cobalt (III) complexes of bis-amidate-bis-alkoxide ligands,(Me4N)[CoIII (L1)](1)
and (Me4N)[CoIII (L2)](2), are synthesized and assessed through a range of characterization …

Energy Landscape for the Electrocatalytic Oxidation of Water by a Single-Site Oxomanganese (V) Porphyrin

D Wang, JT Groves - Inorganic Chemistry, 2022 - ACS Publications
A cationic manganese porphyrin, MnIII-TDMImP, is an efficient, homogeneous, single-site
water oxidation electrocatalyst at neutral pH. The measured turnover frequency for oxygen …

Electrochemical water oxidation using a stable water-soluble mononuclear manganese clathrochelate

S Zheng, X Liang, C Dai, X Yang, Z Li, Y Lai… - New Journal of …, 2023 - pubs.rsc.org
A stable water-soluble mononuclear manganese clathrochelate complex [MnIV (L-6H)] 2− is
utilized as an electrocatalyst for water oxidation in phosphate buffer solution at pH 8.0 …

Homogeneous electrochemical water oxidation catalyzed by cobalt complexes with an amine–pyridine ligand

Y Chen, X Meng, X Chen, X Li, H Ye, S Liu… - Sustainable Energy & …, 2023 - pubs.rsc.org
Efficient water oxidation catalysts are highly desired because of their great significance for
overall water splitting, which is a promising strategy to produce hydrogen on a large scale …

Antiproliferative activity and electrochemical oxygen evolution by Ni (ii) complexes of N′-(aroyl)-hydrazine carbodithioates

R Chaurasia, SK Pandey, DK Singh, MK Bharty… - Dalton …, 2021 - pubs.rsc.org
The electrochemical water splitting by transition metal complexes is emerging very rapidly.
The nickel complexes also play a very vital role in various biological activities. Here, three …

Electrochemical water oxidation catalyzed by a mononuclear cobalt complex of a pentadentate ligand: the critical effect of the borate anion

H Zheng, H Ye, T Xu, K Zheng, X **e, B Zhu… - New Journal of …, 2022 - pubs.rsc.org
Electrochemical water oxidation catalyzed by a cobalt complex,[Co (N3Py2)(H2O)](ClO4) 2
(1)(N3Py2= 2, 5, 8-trimethyl-1, 9-bis (2-pyridyl)-2, 5, 8-triazanonane), is reported. The …