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Understanding ligand-protected noble metal nanoclusters at work
Ligand-protected noble metal nanoclusters, commonly termed 'monolayer-protected metal
clusters'(MPCs), comprise a common set of structures with an inorganic core stabilized by an …
clusters'(MPCs), comprise a common set of structures with an inorganic core stabilized by an …
O2 Activation by Metal Surfaces: Implications for Bonding and Reactivity on Heterogeneous Catalysts
The activation of O2 on metal surfaces is a critical process for heterogeneous catalysis and
materials oxidation. Fundamental studies of well-defined metal surfaces using a variety of …
materials oxidation. Fundamental studies of well-defined metal surfaces using a variety of …
Reactivity of metal clusters
Z Luo, AW Castleman Jr, SN Khanna - Chemical reviews, 2016 - ACS Publications
We summarize here the research advances on the reactivity of metal clusters. After a simple
introduction of apparatuses used for gas-phase cluster reactions, we focus on the reactivity …
introduction of apparatuses used for gas-phase cluster reactions, we focus on the reactivity …
Probing the binding and activation of small molecules by gas-phase transition metal clusters via IR spectroscopy
A Fielicke - Chemical Society Reviews, 2023 - pubs.rsc.org
Isolated transition metal clusters have been established as useful models for extended metal
surfaces or deposited metal particles, to improve the understanding of their surface …
surfaces or deposited metal particles, to improve the understanding of their surface …
CO oxidation as a prototypical reaction for heterogeneous processes
CO oxidation, although seemingly a simple chemical reaction, provides us with a panacea
that reveals the richness and beauty of heterogeneous catalysis. The Fritz Haber Institute is …
that reveals the richness and beauty of heterogeneous catalysis. The Fritz Haber Institute is …
A Ti-anchored Ti 2 CO 2 monolayer (MXene) as a single-atom catalyst for CO oxidation
First-principles computations were performed to investigate the catalytic oxidation of CO on
a Ti-anchored Ti2CO2 monolayer, a typical MXene. The Ti2CO2 monolayer could prevent …
a Ti-anchored Ti2CO2 monolayer, a typical MXene. The Ti2CO2 monolayer could prevent …
Charging Effects on Bonding and Catalyzed Oxidation of CO on Au8 Clusters on MgO
Gold octamers (Au8) bound to oxygen-vacancy F-center defects on Mg (001) are the
smallest clusters to catalyze the low-temperature oxidation of CO to CO2, whereas clusters …
smallest clusters to catalyze the low-temperature oxidation of CO to CO2, whereas clusters …
Unraveling charge state of supported Au single-atoms during CO oxidation
X Zhou, Q Shen, K Yuan, W Yang, Q Chen… - Journal of the …, 2018 - ACS Publications
Thermally stable Au single-atoms supported by monolayered CuO grown at Cu (110) have
been successfully prepared. The charge transfer from the CuO support to single Au atoms is …
been successfully prepared. The charge transfer from the CuO support to single Au atoms is …
Effect of Electronic Structures of Au Clusters Stabilized by Poly(N-vinyl-2-pyrrolidone) on Aerobic Oxidation Catalysis
Au clusters smaller than 1.5 nm and stabilized by poly (N-vinyl-2-pyrrolidone)(PVP) showed
higher activity for aerobic oxidation of alcohol than those of larger size or stabilized by poly …
higher activity for aerobic oxidation of alcohol than those of larger size or stabilized by poly …
Size-specific catalytic activity of polymer-stabilized gold nanoclusters for aerobic alcohol oxidation in water
Gold nanoclusters (ϕ= 1.3 nm) stabilized by poly (N-vinyl-2-pyrrolidone)(Au: PVP NCs)
readily oxidize benzylic alcohols to the corresponding aldehydes and/or carboxylic acids …
readily oxidize benzylic alcohols to the corresponding aldehydes and/or carboxylic acids …