Emerging applications of carbon nanohoops

EJ Leonhardt, R Jasti - Nature Reviews Chemistry, 2019 - nature.com
A cycloparaphenylene can be thought of as the shortest possible cross section of an
armchair carbon nanotube. Although envisioned decades ago, these molecules—also …

Fluorescent cyclophanes and their applications

I Roy, AHG David, PJ Das, JP David… - Chemical Society …, 2022 - pubs.rsc.org
With the serendipitous discovery of crown ethers by Pedersen more than half a century ago
and the subsequent introduction of host–guest chemistry and supramolecular chemistry by …

Chemical synthesis of carbon nanorings and nanobelts

Y Li, H Kono, T Maekawa, Y Segawa… - Accounts of Materials …, 2021 - ACS Publications
Conspectus The discovery and creation of new forms of carbon have always transformed the
scientific landscape. For example, the discoveries of fullerenes, carbon nanotubes (CNTs) …

Topological molecular nanocarbons: All-benzene catenane and trefoil knot

Y Segawa, M Kuwayama, Y Hijikata, M Fushimi… - Science, 2019 - science.org
The generation of topologically complex nanocarbons can spur developments in science
and technology. However, conventional synthetic routes to interlocked molecules require …

Cycloparaphenylenes and related nanohoops

SE Lewis - Chemical Society Reviews, 2015 - pubs.rsc.org
The first synthesis of a cyclic oligophenylene possessing a radial π system was reported in
2008. In the short period that has elapsed since, there has been an ever-increasing level of …

The dynamic, size-dependent properties of [5]–[12] cycloparaphenylenes

ER Darzi, R Jasti - Chemical Society Reviews, 2015 - pubs.rsc.org
[n] Cycloparaphenylenes (or “carbon nanohoops”) are cyclic fragments of carbon nanotubes
that consist of n para linked benzene rings. These strained, all sp2 hybridized macrocycles …

Conjugated nanohoops incorporating donor, acceptor, hetero‐or polycyclic aromatics

M Hermann, D Wassy, B Esser - … Chemie International Edition, 2021 - Wiley Online Library
In the last 13 years several synthetic strategies were developed that provide access to [n]
cycloparaphenylenes ([n] CPPs) and related conjugated nanohoops. A number of potential …

Design and synthesis of carbon nanotube segments

Y Segawa, A Yagi, K Matsui… - Angewandte Chemie …, 2016 - Wiley Online Library
The selective and predictable synthesis of structurally uniform carbon nanotubes (CNTs)
represents a long‐standing goal in both nanocarbon science and synthetic organic …

Circularly polarized luminescence in a Möbius helicene carbon nanohoop

J Malinčík, S Gaikwad, JP Mora‐Fuentes… - Angewandte Chemie …, 2022 - Wiley Online Library
We present the first helicene carbon nanoohop that integrates a [6] helicene into [7]
cycloparaphenylene. The [6] helicene endows the helicene carbon nanohoop with …

Circularly polarized luminescence in chiral π‐conjugated macrocycles

M Hasegawa, Y Nojima, Y Mazaki - ChemPhotoChem, 2021 - Wiley Online Library
The design and synthesis of novel π‐conjugated macrocycles have been an attractive topic
in synthetic chemistry and material and supramolecular chemistry. The distortion caused by …