One-pot reactions elaborated around transition metal-catalyzed isomerization of alkenes not
only offer the inherent advantages of atom-, step-and redox-economy but also enable the …

In this digest, we report the recent advances in asymmetric isomerization of allylic alcohols.
We present the different aspects of this asymmetric transformation that include the diastereo …

Catalytic carbon–nitrogen bond formation in hydrocarbons is an appealing synthetic tool to
access valuable nitrogen-containing compounds. Although a number of synthetic …

Palladium nanoparticles have been immobilized into an amino‐functionalized metal–
organic framework (MOF), MIL‐101Cr‐NH2, to form Pd@ MIL‐101Cr‐NH2. Four materials …

A mild base-catalyzed strategy for the isomerization of allylic alcohols and allylic ethers has
been developed. Experimental and computational investigations indicate that transition …

A dual Ni/Rh catalysis sequence toward α-quaternary aldehydes is reported. An
intramolecular approach from allyl propargyl carbonates alongside the intermolecular …

Ru (IV)-Catalysed redox isomerisation of allylic alcohols has, for the first time, been
successfully assembled with the chemoselective addition of organolithium or …

A photoredox-mediated protocol for the synthesis of α-alkoxy-β-ketosulfoxides and α, β-
dialkoxysulfoxides using alkynes, thiol, and alcohols is reported. This work presents a rare …

The ruthenium‐catalyzed redox isomerization of allylic alcohols was successfully coupled
with the enantioselective enzymatic ketone reduction (mediated by KREDs) in a concurrent …

A protocol for the C–H activation/iodination of benzoic acids catalyzed by a simple iridium
complex has been developed. The method described in this paper allows the ortho-selective …